Three Polyhedron-Based Metal–Organic Frameworks Exhibiting Excellent Acetylene Selective Adsorption
Xia Zhou,
Zitong Song,
Rajamani Krishna
et al.
Abstract:The separation of acetylene (C 2 H 2 ) from ethylene (C 2 H 4 ) and ethane (C 2 H 6 ) is crucial for the production of high-purity C 2 H 2 and the recovery of other gases. Polyhedron-based metal−organic frameworks (PMOFs) are characterized by their spacious cavities, which facilitate gas trapping, and cage windows with varying sizes that enable gas screening. In this study, we carefully selected a class of PMOFs based on V-type tetracarboxylic acid linker (JLU-Liu22 containing benzene ring, JLU-Liu46 containin… Show more
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