Three new inorganic–organic hybrid compounds constructed from two kinds of octamolybdate clusters and flexible multidentate N-donor ligand: syntheses, structures, electrochemistry, luminescence, and photocatalytic properties

Highly Efficient and Uncommon Photoluminescence Behavior Combined with Multiple Dielectric Response in Manganese(II) Based Hybrid Phase Transition Compounds

“…Since high quantum efficiency and tunable optical properties are important indicators for evaluating the performance of PL materials, multifarious approaches have been devoted to the design of such excellent luminescent materials including constructing quantum dot, rare earth doping and organic‐inorganic hybridization, etc . Among them, organic‐inorganic hybrid proven to be one of the most effective methods to prepare superior function PL materials . On the one hand, the high quantum yield of the hybrid PL material is not affected by the size effect and the doping concentration .…”

Various amide-derived ligands induced five octamolybdate-based metal–organic complexes: synthesis, structure, electrochemical sensing and photocatalytic properties

“…Rational design and assembly of polyoxometalate (POM)based metal-organic complexes (MOCs) are of overwhelming interest due to their diverse and fantastic structures, as well as their multifunctional applications in traditional and emerging fields of medicine, electrochemistry, catalysis, magnetism, etc. [1][2][3][4] Of the multitudinous POM family, octamolybdate has exhibited ten isomers so far, namely, α-, β-, γ-, δ-, ε-, ζ-, ξ-, η-, θand ι-isomer, [5][6][7][8][9][10] which can provide plentiful terminal or bridging oxygen atoms to link with transition metal cations and organic ligands during the reaction process, [11][12][13] indicating that the octamolybdates could be taken as structural units to prepare POM-based MOCs with diverse structures. [14][15][16][17] Currently, plenty of N-containing organic ligands have been considered as sensible candidates in establishing various POM-based MOCs, because of their various coordination modes.…”

A novel organic–inorganic hybrid polyoxometalate for the selective adsorption/isolation of β-lactoglobulin

“…24,25 It is known that the N-donor ligands are crucial for the design and synthesis of inorganic-organic hybrids. 26 Compared with the benzene-centered triangular ligands, N-centered ligands, such as tri(4-pyridylphenyl)amine (TPPA), are more ''ductile'' for tailoring to the shape of metal cations. [27][28][29] b-Lactoglobulin (b-Lg) is a major milk allergen in bovine milk.…”