Modern Heterocyclic Chemistry 2011
DOI: 10.1002/9783527637737.ch2
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Three‐Membered Heterocycles. Structure and Reactivity

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Cited by 14 publications
(7 citation statements)
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References 824 publications
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“…Heterocyclic compounds play essential roles in numerous aspects of chemistry . The incorporation of heavier main group elements into heterocycles has provided properties well-suited to electronic, optical, biological, pharmaceutical, material, and catalytic applications. , Despite such utility, synthetic studies of such heavier atom heterocycles are limited by the lack of suitable precursors and efficient synthetic routes …”
Section: Introductionmentioning
confidence: 99%
“…Heterocyclic compounds play essential roles in numerous aspects of chemistry . The incorporation of heavier main group elements into heterocycles has provided properties well-suited to electronic, optical, biological, pharmaceutical, material, and catalytic applications. , Despite such utility, synthetic studies of such heavier atom heterocycles are limited by the lack of suitable precursors and efficient synthetic routes …”
Section: Introductionmentioning
confidence: 99%
“…Ligated boriranes (borirane–Lewis base complexes) are isoelectronic with cyclopropane, aziridine, and oxirane (Figure a), but again little is known about their chemistry . One of the most common reactions of three-membered rings is ring opening with nucleophiles, either directly or with assistance of Brønsted or Lewis acids . To the best of our knowledge, there are no such ring-opening reactions of ligated boriranes, and it is not clear that they are viable.…”
Section: Introductionmentioning
confidence: 99%
“…Among them, three-membered heterocycles containing a chalcogen are ubiquitous subunits, and significant efforts have been dedicated to the development of synthetic methods for oxiranes 12,13 . The sulfur congeners, thiiranes are also useful synthetic precursors that can be transformed into an array of functional groups via ring-opening or desulfurization [14][15][16][17][18][19][20] . In addition, versatile sulfur-containing polymers can be produced via ring-expansion polymerizations or copolymerizations [21][22][23][24][25] .…”
mentioning
confidence: 99%