Three in One: Three Different Molybdates Trapped in a Thiacalix[4]arene Protected Ag72 Nanocluster for Structural Transformation and Photothermal Conversion
Zhi Wang,
Yan‐Jie Zhu,
Olli Ahlstedt
et al.
Abstract:Polyoxometalates (POMs) represent crucial intermediates in the formation of insoluble metal oxides from soluble metal ions, however, the rapid hydrolysis‐condensation kinetics of MoVI or WVI makes the direct characterization of coexisted molecular species in a given medium extremely difficult. Silver nanoclusters have shown versatile capacity to encapsulate diverse POMs, which provides an alternative scene to appreciate landscape of POMs in atomic precision. Here, we report a thiacalix[4]arene protected silver… Show more
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