Three-Dimensional Visualization of Adsorption Distribution in a Single Crystalline Particle of a Metal–Organic Framework
Emina Yamada,
Hirotoshi Sakamoto,
Hirosuke Matsui
et al.
Abstract:Many unique adsorption properties of metal− organic frameworks (MOFs) have been revealed by diffraction crystallography, visualizing their vacant and guest-loaded crystal structures at the molecular scale. However, it has been challenging to see the spatial distribution of the adsorption behaviors throughout a single MOF particle in a transient equilibrium state. Here, we report three-dimensional (3D) visualization of molecular adsorption behaviors in a single crystalline particle of a MOF by in situ X-ray abs… Show more
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