“…Photochromism has attracted much attention because of their potential applicability to photonic devices, such as optical memories − and photooptical switches. − Among a number of photochromic compounds, diarylethene derivatives are the most promising compounds for these applications because of high durability for coloring/decoloring cycles, thermal stability of both isomers, and rapid response. − Single-crystalline photochromism is also a unique character of diarylethene derivatives. We have reported some 1,2-bis(3-thienyl)perfluorocyclopentene derivatives that undergo single-crystalline photochromism. ,− Both photocyclization and photocycloreversion processes of 1,2-bis(2,5-dimethyl-3-thienyl)perfluorocyclopentene crystals have been elucidated in situ by X-ray crystallographic analysis. , …”