Three-dimensional Na3V2(PO4)3@carbon/N-doped graphene aerogel: A versatile cathode and anode host material with high-rate and ultralong-life for sodium storage

Ling, Rui; Cao, Bingqiang; Qi, Wentao; Yang, Chao; Shen, Kaier; Sang, Zhiyuan; Guo, Jinze; Xie, Dongli; Cai, Shu; Sun, Xiaohong

doi:10.1016/j.jallcom.2021.159307

Cited by 27 publications

(19 citation statements)

References 47 publications

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“…A price comparison gives 0.08$/equivalent for Sodium whereas 0.50$/equivalent for Li, 78 and is easily recyclable too 10,79‐82 . While making use of the SIB technology, although it provides the same intercalation chemistry as Li + 82,83 and storage mechanism, 84 the major challenge incurred is the sluggish Na + diffusion caused by a higher ionic radius of Na + (0.98 Å) in contrast with Li + (0.69 Å) 10,72,85,86 leading to large volume changes, low rate capability, and capacity fading during cycling 75,83,85,87 . A lot of research is being done to overcome these drawbacks in Na‐based batteries.…”

Section: Symmetric Electrode Materials In Sodium‐ion Batteriesmentioning

confidence: 99%

“…Similar to these, various other studies were carried out such as in situ carbon layers combined with NVP giving a 3D skeleton structure, carbon layer combined with nitrogen (N) doped graphene Aerogel (NVP@C/N‐GA), double carbon embedding on NVP (DC‐NVP). These works reported improved electrochemical performance, specifically in terms of performance at high C rates and good rate capability 7,85,93 . The carbon sources used in the synthesis were different for each group.…”

Section: Symmetric Electrode Materials In Sodium‐ion Batteriesmentioning

confidence: 99%

“…74,76,77 A price comparison gives 0.08$/equivalent for Sodium whereas 0.50$/equivalent for Li, 78 and is easily recyclable too. 10,[79][80][81][82] While making use of the SIB technology, although it provides the same intercalation chemistry as Li +82,83 and storage mechanism, 84 the major challenge incurred is the sluggish Na + diffusion caused by a higher 75,83,85,87 A lot of research is being done to overcome these drawbacks in Na-based batteries. Similar to the interest in Li-ion symmetric systems, different materials in Na-based symmetric systems have been subjected to research.…”

Section: Symmetric Electrode Materials In Sodium-ion Batteriesmentioning

confidence: 99%

“…In the NASICON materials, the lantern structured Na 3 V 2 (PO 4 ) 3 (NVP), 86 which has high Na + mobility and structural stability due to a large number of interstitial sites for Na + ion migration, 90,91 is a very attractive material for battery applications. 10,78 When used as a cathode, it shows a plateau at a high potential of 3.4 V with V 3+ / V 4+ redox couple, 92 and as an anode, it exhibits two redox potentials at low voltages of 1.6 V and 0.3 V vs V 3+ /V 2+ , rendering its ability to be used as both anode and cathode, 10,85,87,90 thus finding their use extensively in symmetric battery systems.…”

Section: Nasicon Structured Nvpmentioning

confidence: 99%

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Utilization of symmetric electrode materials in energy storage application: A review

Moossa

Abraham

Kahraman

et al. 2022

Intl J of Energy Research

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The development of efficient energy storage systems is an important field of research in the modern era where fossil fuels are headed toward depletion. The invention of batteries is regarded as one of the most significant advancements in the field of energy storage. From its inception, a lot of research has been done and is still being carried out to develop novel and advanced materials that provide improved performance in terms of capacity, stability, and cost. In this context, symmetric or bipolar electrodes, which utilize the same material for the anode and the cathode, emerge as a suitable solution for battery technology. In this work, different types of symmetric electrode materials for batteries are subjected to review. The various structures, methods of synthesis, and characteristics are analyzed and presented. The Na 3 V 2 (PO 4 ) 3 (NVP) is the most widely analyzed symmetric material among all the symmetric materials. The Na-based systems are widely studied in symmetric configurations for their resource availability and price economics advantages. Aqueous and solid-state symmetric batteries are the emerging systems in symmetric batteries. This review will provide insights to battery researchers involved in bipolar material design and shed light on new emerging energy storage techniques.

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Section: Symmetric Electrode Materials In Sodium‐ion Batteriesmentioning

confidence: 99%

Section: Symmetric Electrode Materials In Sodium‐ion Batteriesmentioning

confidence: 99%

Section: Symmetric Electrode Materials In Sodium-ion Batteriesmentioning

confidence: 99%

Section: Nasicon Structured Nvpmentioning

confidence: 99%

See 2 more Smart Citations

Utilization of symmetric electrode materials in energy storage application: A review

Moossa

Abraham

Kahraman

et al. 2022

Intl J of Energy Research

View full text Add to dashboard Cite

show abstract

“…The symmetric systems with the same intercalation compound are often with low energy density and requires the same materials with distinct redox couples, which are active in low- and high-voltage ranges [ 21 ]. Various LIBs and SIBs have been proposed with the symmetric configurations of Li 3 V 2 (PO 4 ) 3- (LVP) [ 24 , 25 , 26 , 27 ] and Na 3 V 2 (PO 4 ) 3- (NVP) [ 27 , 28 ], with modifications to them such as composite formation with carbon nanotubes, carbon black [ 29 ], Na 2 VTi(PO 4 ) 3 [ 30 ], Na 3 MnTi(PO 4 ) 3 [ 31 ], Na 2 VTi(PO 4 ) 3 [ 32 ], Na 3 Co 0.5 Mn 0.5 Ti(PO 4 ) 3 [ 33 ], Na 3 V 2 (PO 4 ) 2 F 3 @C-rGO [ 9 ], Na 3 V 2 (PO 4 ) 3 /C [ 34 ], K + - and Mg + -doped NVP [ 35 ], double-carbon-embedded NVP [ 36 ], Li-containing symmetric material Li 9 V 3 (P 2 O 7 )(PO 4 ) 2 [ 37 ], Li- and Mn-rich layered oxide 0.3 Li 2 MnO 3 ·0.7 LiNi 1/3 Co 1/3 Mn 1/3 O 2 [ 21 ], and Al- and Fe-doped Li 3 V 2 (PO 4 ) 3 [ 38 ].…”

Section: Introductionmentioning

confidence: 99%

Electrochemical Performance of Na3V2(PO4)2F3 Electrode Material in a Symmetric Cell

Abraham

Moossa

Tariq

et al. 2021

IJMS

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A NASICON-based Na3V2(PO4)2F3 (NVPF) cathode material is reported herein as a potential symmetric cell electrode material. The symmetric cell was active from 0 to 3.5 V and showed a capacity of 85 mAh/g at 0.1 C. With cycling, the NVPF symmetric cell showed a very long and stable cycle life, having a capacity retention of 61% after 1000 cycles at 1 C. The diffusion coefficient calculated from cyclic voltammetry (CV) and the galvanostatic intermittent titration technique (GITT) was found to be ~10−9–10−11, suggesting a smooth diffusion of Na+ in the NVPF symmetric cell. The electrochemical impedance spectroscopy (EIS) carried out during cycling showed increases in bulk resistance, solid electrolyte interphase (SEI) resistance, and charge transfer resistance with the number of cycles, explaining the origin of capacity fade in the NVPF symmetric cell. Finally, the postmortem analysis of the symmetric cell after 1000 cycles at a 1 C rate indicated that the intercalation/de-intercalation of sodium into/from the host structure occurred without any major structural destabilization in both the cathode and anode. However, there was slight distortion in the cathode structure observed, which resulted in capacity loss of the symmetric cell. The promising electrochemical performance of NVPF in the symmetric cell makes it attractive for developing long-life and cost-effective batteries.

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Advances and Challenges of Porous Structure on Solid–Liquid Interfaces in Polyanionic Sodium‐Ion Batteries

Zhao,

Dong,

Xing

et al. 2024

Advanced Energy Materials

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The sodium‐ion batteries (SIBs) are expected to be the substitute for lithium‐ion batteries (LIBs) because of their low cost, high abundance, and similar working mechanism. Among them, polyanion‐type electrodes show great application prospects due to their superior ion diffusion channels and structural stability. However, there are still many scientific issues that need to be thoroughly investigated, especially the formation mechanism, structural stability, and interface impedance of solid–liquid interfaces. Therefore, it is of great significance to systematically study the mechanism of interface reaction and the electrochemical behavior, to promote the further practical application of SIBs. Fortunately, the polyanionic electrodes can effectively improve the transport dynamics and the interfacial stability of the solid–liquid interfaces through constructing the porous structure, surface modification, and electrolyte strategies, thus improving the cycle and rate performance. This review discusses the characteristics and formation mechanisms of electrode/electrolyte interface (EEI), as well as their electrochemical behavior in porous structures with different dimensions. Furthermore, this review covers the application of porous materials in improving transport kinetics and EEI. In particular, it highlights the various strategies employed to comprehend the interplay among structure, chemistry, preparation methods, and the mechanisms of porous electrodes that ultimately affect the electrochemical properties of SIBs.

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Three-dimensional Na3V2(PO4)3@carbon/N-doped graphene aerogel: A versatile cathode and anode host material with high-rate and ultralong-life for sodium storage

Cited by 27 publications

References 47 publications

Utilization of symmetric electrode materials in energy storage application: A review

Utilization of symmetric electrode materials in energy storage application: A review

Electrochemical Performance of Na3V2(PO4)2F3 Electrode Material in a Symmetric Cell

Advances and Challenges of Porous Structure on Solid–Liquid Interfaces in Polyanionic Sodium‐Ion Batteries

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