Three Copper(II) Complexes of a “Tritopic” Hydrazone Ligand: Synthesis and Structural Characterization

Qin, Suni; Nie, Chuanli; Weng, Zhehui; Chen, Zilu; Liang, Fu‐Pei

doi:10.1002/zaac.201100148

Cited by 5 publications

(2 citation statements)

References 36 publications

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“…Although some similar complexes are known, none of them have ever been used for catalytic studies. 13 Therefore, these complexes are ideal candidates to understand the influence of different coordination environments of metal ions for photo-catalytic studies. The present report emphasizes the role of different coordination environments (role of coordinated water/solvent molecules and different donor sites of ligands) of one-dimensional Cu(II) coordination polymers in photo-catalytic activities.…”

Section: Introductionmentioning

confidence: 99%

The influence of different coordination environments on one-dimensional Cu(ii) coordination polymers for the photo-degradation of organic dyes

Hussain

Bhardwaj

2016

Dalton Trans.

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Three new Cu(ii) coordination polymers, namely, {[Cu3(L(1))(NO3)2(DMF)(H2O)]·3(DMF)}n (), [Cu3(L(1))(Cl)2(DMF)2]n () and [Cu3(L(2))(NO3)4(H2O)4]n (), were synthesized from pyridine-2,6-dicarbohydrazide based imine linked tritopic ligands. All the complexes were characterized using elemental analysis, IR, UV-vis spectroscopy and ESI-MS. The solid state structures of complexes were determined using single crystal X-ray crystallography. The complexes contain trinuclear copper units connected through different anions that lead to the formation of one dimensional (ID) chain structures. Depending upon the anion of the copper salt and donor atoms of the ligands used in complexation, a small variation in the structures was observed. In complex , the trinuclear copper units are connected by phenoxo-bridging (μ2-O(-)) along with one coordinated water molecule, whereas complex is connected through chloride bridging (μ2-Cl) and complex is connected through nitrate ions (μ-[O-N-O]) along with four water molecules. Photo-catalytic activities of the synthesized complexes () were investigated. All the complexes were found to be photo-catalytically active; however, the distinct coordination environment of the metal ions (i.e. difference in the coordinated water molecules and donor sites of ligands) played a significant role in the catalytic activities. Therefore, this study presents comparative photo-catalytic studies of different coordination environments of metal ions in one-dimensional Cu(ii) coordination polymers. The results provide a potential pathway for the rational design of more efficient photo-catalysts.

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Section: Introductionmentioning

confidence: 99%

The influence of different coordination environments on one-dimensional Cu(ii) coordination polymers for the photo-degradation of organic dyes

Hussain

Bhardwaj

2016

Dalton Trans.

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“…The structural variants are characterized by a bimodal distribution in the lengths of this additional interaction, with distances ranging between 2.6 and 2.9 and 3.0–3.3 Å (Figure S4). Among the structures that form this MBB, the majority are 0D compounds with only 6 forming coordination polymers. ,− Study of the gas sorption properties in this family of materials has not been reported, a matter that is addressed herein.…”

Section: Introductionmentioning

confidence: 99%

Dinuclear Copper Sulfate-Based Square Lattice Topology Network with High Alkyne Selectivity

Andaloussi,

Sensharma,

Bezrukov

et al. 2024

Crystal Growth & Design

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Porous coordination networks (PCNs) sustained by inorganic anions that serve as linker ligands can offer high selectivity toward specific gases or vapors in gas mixtures. Such inorganic anions are best exemplified by electron-rich fluorinated anions, e.g., SiF6 2–, TiF6 2–, and NbOF5 2–, although sulfate anions have recently been highlighted as inexpensive and earth-friendly alternatives. Herein, we report the use of a rare copper sulfate dimer molecular building block to generate two square lattice, sql, coordination networks which can be prepared via solvent layering or slurrying, CuSO4(1,4-bib)1.5, 1, (1,4-bib = 1,4-bisimidazole benzene) and CuSO4(1,4-bin)1.5, 2, (1,4-bin = 1,4-bisimidazole naphthalene). Variable-temperature SCXRD and PXRD experiments revealed that both sql networks underwent reversible structural transformations due to linker rotations or internetwork displacements. Gas sorption studies conducted upon the narrow-pore phase of CuSO4(1,4-bin)1.5, 2np, found a high calculated 1:99 selectivity for C2H2 over C2H4 (33.01) and CO2 (15.18), as well as strong breakthrough performance. Across-the-board, C3H4 selectivity vs C3H6, CO2, and C3H8 was also observed. Sulfate-based PCNs, although still understudied, appear increasingly likely to offer utility in gas and vapor separations.

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Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol

Lukov

Tsaturyan

Tupolova

et al. 2019

Mendeleev Communications

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Three Copper(II) Complexes of a “Tritopic” Hydrazone Ligand: Synthesis and Structural Characterization

Cited by 5 publications

References 36 publications

The influence of different coordination environments on one-dimensional Cu(ii) coordination polymers for the photo-degradation of organic dyes

The influence of different coordination environments on one-dimensional Cu(ii) coordination polymers for the photo-degradation of organic dyes

Dinuclear Copper Sulfate-Based Square Lattice Topology Network with High Alkyne Selectivity

Crystal structure and nontrivial magnetic properties of CuII binuclear complex based on 4-methyl-2,6-bis{[2-(4,6-dimethyl-pyrimidin-2-yl)hydrazono]methyl}phenol

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