It has been increasingly becoming clear that Casimirand Casimir-Polder entropies may be negative in certain regions of temperature and separation. In fact, the occurrence of negative entropy seems to be a nearly ubiquitous phenomenon. This is most highlighted in the quantum vacuum interaction of a nanoparticle with a conducting plate or between two nanoparticles. It has been argued that this phenomenon does not violate physical intuition, since the total entropy, including the self-entropies of the plate and the nanoparticle, should be positive. New calculations, in fact, seem to bear this out at least in certain cases.
The thermal Casimir puzzleFor 15 years there has been a controversy surrounding entropy in the Casimir effect. This is most famously centered around the issue of how to describe a real metal, in particular, the permittivity ε(ω) at zero frequency [1]. The latter determines the low-temperature and high temperature corrections to the free energy, and hence to the entropy. The issue involves how ω 2 ε(ω) behaves as ω → 0.Dissipation or finite conductivity implies this vanishes; this leads to a linear temperature dependence at low temperature, and a reduction of the high-temperature force. Most experiments [2-4], but not all [5], favor the nondissipative plasma model! For an overview of the status of both theory and experiment, see Ref.[6].The Drude model, and general thermodynamic and electrodynamic arguments, suggest that the transverse electric (TE) reflection coefficient at zero frequency for a good, but imperfect, metal plate should vanish. Careful calculations for lossy parallel plates show that at very low temperature the free energy approaches a constant quadratically in the temperature, thus forcing the entropy to vanish at zero temperature [7]. Thus, there is no violation of the third law of thermodynamics. However, there would persist a region at low temperature in which the entropy would be negative. This was not thought to be a problem, since the interaction Casimir free energy does not describe the entire system of the Casimir apparatus, whose total entropy must necessarily be positive. The physical basis for the negative entropy region remains somewhat mysterious. Here we address negative entropy arising from geometry. The interplay of geometry and material properties is further explored in Ref. [8].For some time it has been known that negative entropy regions can emerge geometrically. For example, when a perfectly conducting sphere is near a perfectly conducting plate, the entropy at room temperature can turn negative, with enhancement of the effect occurring for smaller spheres [9]. The occurrence of negative interaction entropies for a small sphere in front of a plane or another sphere is illustrated in Fig. 1 within the dipole and single-scattering approximation. Since the negative entropy region is enhanced by making the sphere small, this suggests that the phenomena be explored by considering the dipole approximation only. That is, we will examine point particles, atoms or nanopa...