2008
DOI: 10.1209/0295-5075/83/67006
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Thorium-doping–induced superconductivity up to 56 K in Gd 1−x Th x FeAsO

Abstract: We report a new strategy to induce superconductivity in iron-based oxyarsenide. Instead of F − substitution for O 2− , we employed Th 4+ doping in GdFeAsO with the consideration of "lattice match" between Gd2O2 layers and Fe2As2 ones. As a result, superconductivity with T onset c as high as 56 K was realized in a Gd0.8Th0.2FeAsO polycrystalline sample. This Tc value is among the highest ever discovered in the iron-based oxypnictides.

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Cited by 643 publications
(535 citation statements)
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“…The highest T c reached 57 K to date in the F doped SmFeAsO, which crystallizes into the ZrCuSiAs-type structure [2,3]. Subsequently, many related Fe based compounds comprising the Fe 2 X 2 layer (X: pnictogen or chalcogen) and some were found to show SC by chemical or physical doping within first few years.…”
Section: Introductionmentioning
confidence: 99%
“…The highest T c reached 57 K to date in the F doped SmFeAsO, which crystallizes into the ZrCuSiAs-type structure [2,3]. Subsequently, many related Fe based compounds comprising the Fe 2 X 2 layer (X: pnictogen or chalcogen) and some were found to show SC by chemical or physical doping within first few years.…”
Section: Introductionmentioning
confidence: 99%
“…Since the discovery of superconductivity in LaFeAs(O 1−x F x ) [1], high transition temperatures (T c ) up to 56 K have been reported in the doped Fe-based oxypnictides [2,3,4,5,6,7,8,9]. The new high-temperature superconductivity in Fe-pnictides has attracted tremendous interests both experimentally and theoretically.…”
Section: Introductionmentioning
confidence: 99%
“…15 Almost five years since the initial discovery, the maximum T c in bulk Fe-SCs remains capped at B57 K for Sm 0. 95 17 while superconductivity up to 65 K has very recently been reported in single layer FeSe films. 18 Unconventional superconductivity is also present in some of the strongly-correlated heavy-fermion materials (HFs).…”
Section: Jennifer E Hoffmanmentioning
confidence: 99%