Tlre qnantum systems helium and hydrogen provide a versatile testing ground for studying interfacial phenomena.As examples, both some properties of surface< near thermodynamic equilibrium, like layering and wetting, and uonequilibrium states of qucnch-condensed disordered films are discussed. A further topic is the development of macroscopic instabilities of interfaces under external perturbation.
I. Introdrrction
TI. Quantum Films Close to EquilibriumSurface phenomena of condensed quantum matter, mostly helium and hydrogen, have raised considerable interest in recent years for a number of reasons. Although not very important for direct applications, these systems display several propertie? which make them ideal candidates for fundamental studies. Since the interactions between the simple atoms and molecules under consideration are accersible from a b initio calculations, good quantitative comparisons between theory and experiments should be possible. Furthermore the systems can be prepared in general under extremely pure and well-defined conditions, As a result of the small mass and low interaction energies, effects due to zero point motion should be particularly prominent in these quantum liquids and solids. The superfIuid transitions in 3~e and 4~e , resulting from quantum stati~tics, add to the intriguing properties of these systems, and there are various novel interfacial phenomena, like melting-crystallization waves, which for various reasons have so far only been observed in quantum systems.Thin film5 of helium and hydrogen with a thickness in the monolayer range have been studied quite thoroughly, both regarding structure and excitations, by means of neutron scattering, specific heat, third sound etc., in particular on substrates with large surface area like exfoliated graphite, as described in several review articles [I]. Here we focus on investigations of films with a thickness beyond 1 monolayer, concentrating on phenomena like layering and wetting, and the annealing of disordered films. At the end we shall also consider the stability of the surfaces of the bulk solid and liquid phases with respect to external perturbations, like electrostatic pressure, and illustrate the formation of surface patterns developing as the system is driven beyond the stability threshold. Due to space limitations only part of the work done on these topics can be presented here, and the selection is certainly biased, most of the examples being taken from our own investigations. Important subjects, in particular the roughening transitions of solid-liquid He interfaces, which are not treated here, have been reviewed elsewhere in the literature [2]. The wetting behavior of He on alkali metals, another question which has raised a large amount of intere~t recently, is discu~sed in this volume by Taborek [ 3 ] .In this section we di~cuss yome structural and dynamic properties of helium and hydrogen surfaces close to thermodynamic equilibrium. In many respects the two materials are qualitatively similar; others, like superfluidit...