“…The computed electronic energies of gauche(1) and gauche(2) are very similar, and ca. 0.3 kcal/mol lower than those of gauche(3) and anti (1). Inclusion of zero-point vibrational energies does not significantly affect the relative energies.…”
Section: Vibrational Spectrum Of S-isopropyl Propane-2-thiosulfonate (3)mentioning
confidence: 79%
“…Thiosulfonate S-esters (general formula: R 1 ASO 2 ASAR 2 ) are of interest as reactive and synthetically useful reagents in general and industrial organic chemistry [1], as powerful sulfenylation reagents [2], and as blocking agents in protein chemistry [3]. Since thiosulfonate S-esters are commercially available only to a very limited extent, the synthetic accessibility of these compounds, in particular via modern environmentally friendly methods, is still of importance [4].…”
“…The computed electronic energies of gauche(1) and gauche(2) are very similar, and ca. 0.3 kcal/mol lower than those of gauche(3) and anti (1). Inclusion of zero-point vibrational energies does not significantly affect the relative energies.…”
Section: Vibrational Spectrum Of S-isopropyl Propane-2-thiosulfonate (3)mentioning
confidence: 79%
“…Thiosulfonate S-esters (general formula: R 1 ASO 2 ASAR 2 ) are of interest as reactive and synthetically useful reagents in general and industrial organic chemistry [1], as powerful sulfenylation reagents [2], and as blocking agents in protein chemistry [3]. Since thiosulfonate S-esters are commercially available only to a very limited extent, the synthetic accessibility of these compounds, in particular via modern environmentally friendly methods, is still of importance [4].…”
“…2 Furthermore, the thiosulfonates have a wide industrial application both in polymer production and in photographic processes. 3 Due to their stronger sulfenylating power, thiosulfonates have also been extensively utilized in organic syntheses for sulfide and disulfide formation or aromatic thiocyanation with the thiolate anion. 4 Several synthetic methods for the preparation of unsymmetrical thiosulfonates possessing various substituents at the sulfenyl sulfur atom have been reported.…”
Thiosulfonates were prepared by the iodine oxidative sulfenylation of sulfinates with various disulfides in good yields both in the presence and absence of solvent. One of the important biological applications of sulfenylation is the reaction of cyclic disulfides.
“…81 7.28.2.2 Oxidation of Thiols to Thiosulphonates, Sulfonyl Chlorides, Sulfonamides, and Sulfonic Acids Thiosulfonates 7 serve as useful compounds in the industry, 82 show some biological activity, 83 and are employed as strong sulfenylating agents. 84 Several pharmaceutically active compounds used in the prevention and treatment of important diseases contain the sulfonamide group.…”
Section: By Chemical Reagents Enzymatic Systems and Other Methodsmentioning
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