“…Hydrogen is omitted. Solvothermal conditions can yield highly crystalline MOFs in 48 h. Reproduced with permission ( Yuan et al., 2022 ); Copyright, 2022 Elsevier Inc. …”
Section: Step-by-step Methods Detailsmentioning
confidence: 99%
“…Therefore, in this protocol, we synthesize UiO-66 type MOFs from the Zr cluster and 2,5-dichloroterephthalic acid (H 2 BDC-Cl 2 ) under solvothermal conditions and then further post-functionalize with 1,2-Ethanedithiol (EDT) ( Scheme 1 ) to introduce the thiol chelation groups to boost the Fe 3+ removal efficiency. Further knowledge of solvothermal synthesis and post-functionalization procedures can be found in the literature ( Yuan et al., 2022 ). Scheme 1 Synthesis of UiO-66 MOF and post functionalization Oxygen is shown in red; zirconium in light blue; carbon in gray; and chlorine in green.…”
Section: Before You Beginmentioning
confidence: 99%
“…Hydrogen is omitted. Reproduced with permission ( Yuan et al., 2022 ); Copyright, 2022 Elsevier Inc. …”
Section: Before You Beginmentioning
confidence: 99%
“…We provide details of the MOFs synthesis and post-functionalization procedures, and include key performance data of the Zr-MOFs for removing Fe 3+ , which were collected from the inductively coupled plasma-optical emission spectrometer (ICP-OES) and inductively coupled plasma mass spectrometer (ICP-MS). For complete details on the use and execution of this protocol, please refer to Yuan et al. (2022) .…”
mentioning
confidence: 99%
“…For complete details on the use and execution of this protocol, please refer to Yuan et al. (2022) .…”
“…Hydrogen is omitted. Solvothermal conditions can yield highly crystalline MOFs in 48 h. Reproduced with permission ( Yuan et al., 2022 ); Copyright, 2022 Elsevier Inc. …”
Section: Step-by-step Methods Detailsmentioning
confidence: 99%
“…Therefore, in this protocol, we synthesize UiO-66 type MOFs from the Zr cluster and 2,5-dichloroterephthalic acid (H 2 BDC-Cl 2 ) under solvothermal conditions and then further post-functionalize with 1,2-Ethanedithiol (EDT) ( Scheme 1 ) to introduce the thiol chelation groups to boost the Fe 3+ removal efficiency. Further knowledge of solvothermal synthesis and post-functionalization procedures can be found in the literature ( Yuan et al., 2022 ). Scheme 1 Synthesis of UiO-66 MOF and post functionalization Oxygen is shown in red; zirconium in light blue; carbon in gray; and chlorine in green.…”
Section: Before You Beginmentioning
confidence: 99%
“…Hydrogen is omitted. Reproduced with permission ( Yuan et al., 2022 ); Copyright, 2022 Elsevier Inc. …”
Section: Before You Beginmentioning
confidence: 99%
“…We provide details of the MOFs synthesis and post-functionalization procedures, and include key performance data of the Zr-MOFs for removing Fe 3+ , which were collected from the inductively coupled plasma-optical emission spectrometer (ICP-OES) and inductively coupled plasma mass spectrometer (ICP-MS). For complete details on the use and execution of this protocol, please refer to Yuan et al. (2022) .…”
mentioning
confidence: 99%
“…For complete details on the use and execution of this protocol, please refer to Yuan et al. (2022) .…”
Heavy metals, pharmaceuticals, microplastics, dyes, and radionuclides in wastewater increasingly threaten environmental sustainability. Metal‐organic frameworks (MOFs) are versatile materials for mitigating these contaminants through efficient detection, capture, adsorption, and degradation. These crystalline structures, formed by combining metal ions with organic ligands, offer high surface area, tailored porosity, reproducibility, and robust chemical stability. This review compiles recent advancements in MOFs for pollutant removal, highlighting innovations in selective adsorption mechanisms for heavy metals, functionalized MOFs for pharmaceutical and microplastic removal, and enhanced photocatalytic degradation for dyes. Unique to this review is the integration of recent innovations such as ion exchange capabilities and photocatalytic degradation under visible light, addressing advanced applications that significantly enhance pollutant removal efficiency that other reviews have not covered comprehensively. The review also cites our group's recent work on a curcumin‐immobilized zeolitic imidazolate framework‐8 (Cmim@ZIF‐8) nanoprobe, demonstrating high selectivity for Fe2+ ions in water (detection limit: 7.64 μM) and its applicability in live‐cell imaging of HepG2 cells. Advanced techniques like density functional theory (DFT) simulations are employed to elucidate adsorption and degradation mechanisms, bridging theoretical insights with experimental findings. By critically evaluating these developments, the review identifies promising avenues for optimizing MOF design and advancing effective water treatment solutions.
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