Thioetherification of isoprene and butanethiol on transition metal phosphides

Recent Trends in Transition Metal Phosphide (TMP)-Based Seawater Electrolysis for Hydrogen Evolution

“…For instance, the authors in [11] used phosphatization and acidification to create an Ni 2 P-Fe 2 P/NF electrocatalyst with a 2D nanosheet structure. Similarly, the results in [39] demonstrated that the Ni 2 P-Fe 2 P/NF catalyst with a two-dimensional nanosheet structure, prepared using acidification and phosphating methods, exhibited excellent intrinsic activity (Figure 4a).…”

“…Phosphides are the products created when phosphorus is combined with any d-(such as nickel (Ni), molybdenum (Mo), tungsten (W), cobalt (Co), and iron (Fe)) or f-metal. TMPs are resistant metallic substances with acidic as well as metallic sites [39,40]. The metal phosphides react quickly with water and moisture in the air or stored grain to form phosphine gas.…”

Fe‐Induced Electronic Transfer and Structural Evolution of Lotus Pod‐Like CoNiFePx@P,N‐C Heterostructure for Sustainable Oxygen Evolution

“…[32] After phosphating CoNi-MOF, the main XRD peaks of the CoNiP x @P,N-C can be assigned to Co 2 P (PDF#54-0413) and Ni 2 P (PDF#03-0953) (Figure 2a). [18,33] For the phosphating product CoNiFeP x @P,N-C of CoNi-MOF-Fe, in addition to the Co 2 P and Ni 2 P, the diffraction peaks of Fe 2 P (PDF#88-1803) are also detected. [33,34] It can be seen that the addition of iron atoms can induce their nucleation and derivation of new Fe 2 P phases from the separated binary metal phosphide phases (Ni 2 P and Co 2 P), which may provide more abundant types and numbers of active sites.…”

Transition Metal Phosphides (TMP) as a Versatile Class of Catalysts for the Hydrodeoxygenation Reaction (HDO) of Oil-Derived Compounds

“…Phosphorous can adopt any oxidation state between 0 and 3, resulting in a plethora of structural configurations. The TMPs are refractory metallic compounds exhibiting both metallic and acidic sites [44,45] due to the alloying of TM with P atoms (Figure 3); their classification can be found in Table 1, whereas their physical properties are shown in Table 2. Thorough review articles on the structure of TMPs can be found in the literature [46][47][48][49][50][51][52].…”