2019
DOI: 10.1002/asia.201900969
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Thermosetting Shape Memory Polymers and Composites Based on Polybenzoxazine Blends, Alloys and Copolymers

Abstract: When dealing with smart polymers, in particular with shape memory polymers, the polymer type and composition specify the overall material properties and in particular the extent of the shape memory effect. Polybenzoxazines as a polymer with high potential for structural applications represent a promising component for materials with both shape memory effect and structurally interesting material properties. This minireview gives insight into how the shape memory effect, in particular the shape recovery event, i… Show more

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Cited by 26 publications
(23 citation statements)
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“…From the literature, the hard and soft segments are responsible for remembering the initial shape and shape fixation and phase transition, respectively. [49][50] As shown in Figure 3a-(i,ii), when the SSA is adapted against some substrates by external forces in the form of temporary shape (flattened tip), the mechanical energy is stored in the SSA's cross-linking network of hard and soft segments. It generates a strong adhesion to the contact surface.…”
Section: Adaptability Of Ssamentioning
confidence: 99%
“…From the literature, the hard and soft segments are responsible for remembering the initial shape and shape fixation and phase transition, respectively. [49][50] As shown in Figure 3a-(i,ii), when the SSA is adapted against some substrates by external forces in the form of temporary shape (flattened tip), the mechanical energy is stored in the SSA's cross-linking network of hard and soft segments. It generates a strong adhesion to the contact surface.…”
Section: Adaptability Of Ssamentioning
confidence: 99%
“…These values are comparable to those reported for other thermoset composites based on epoxy resins or polybenzoxazines. 194 Although this approach is attractive in terms of synthetic preparation and low costproduction, there still remains a major concern related to the difficult recyclability of thermosetting materials, since most of them are disposed of via incineration or landfilling.…”
Section: Shape-programmable Materialsmentioning
confidence: 99%
“…(c) Main stages of thermally induced shape memory polymers [296]. (d) Classification of shape-changing polymers.…”
Section: Advanced Materials Based Passive Cooling Strategiesmentioning
confidence: 99%