Engineering fibers with nanomaterials is an effective
way to modify
their properties and responses to external stimuli. In this study,
we doped cotton fibers with silver nanoparticles, both on the surface
(126 ± 17 nm) and throughout the fiber cross section (18 ±
4 nm), and examined the resistance to soil biodegradation. A reagent-free
one-pot treatment of a raw cotton fabric, where noncellulosic constituents
of the raw cotton fiber and starch sizing served as reducing agents,
produced silver nanoparticles with a total concentration of 11 g/kg.
In a soil burial study spanning 16 weeks, untreated cotton underwent
a sequential degradation processfibrillation, fractionation,
and mergingcorresponding to the length of the soil burial
period, whereas treated cotton did not exhibit significant degradation.
The remarkable biodegradation resistance of the treated cotton was
attributed to the antimicrobial properties of silver nanoparticles,
as demonstrated through a test involving the soil-borne fungus Aspergillus flavus. The nonlinear loss behavior of
silver from the treated cotton suggests that nanoparticle depletion
in the soil depends on their location, with interior nanoparticles
proving durable against environmental exposure.