We present a linear-response theory for the thermopower of a single-electron transistor consisting of a superconducting island weakly coupled to two normal-conducting leads. The thermopower shows oscillations with the same periodicity as the conductance and is rather sensitive to the size of the superconducting gap ⌬. In particular, the previously studied sawtooth-like shape of the thermopower for a normal-conducting singleelectron device is qualitatively changed even for small gap energies. DOI: 10.1103/PhysRevB.71.220503 PACS number͑s͒: 72.15.Jf, 73.23.Hk, 74.45.ϩc The transport properties of small conducting grains in the Coulomb blockade ͑CB͒ regime have extensively been studied during the past years. This regime is characterized by a unique energy scale, the so-called charging energy E c of the grain ͑see below͒. The most prominent phenomenon is the occurence of CB oscillations in the low-temperature conductance of a small grain weakly coupled to the leads. 1 Recently, thermoelectric effects in single-electron devices such as the thermopower have attracted growing interest.2-11 The thermopower is related to the current that arises due to a finite temperature difference between the two leads.14 It yields additional information about the kinetics of the system as it measures the average energy of the electrons carrying the current through the system. Therefore, some type of electronhole asymmetry in the system is necessary in order to observe a nonvanishing thermopower.In analogy to the CB oscillations of the conductance, the thermopower of a small grain shows oscillations of the same periodicity but with sawtooth-like shape. 2,3 In contrast to the conductance this dependence on the external gate voltage is very sensitive to the conditions under which the thermoelectric transport occurs. This sensitivity has been demonstrated, e.g., for the transition from the sequential tunneling regime to the cotunneling regime. 4,5 Recently, the thermopower of open quantum dots with strong coupling to the leads was investigated.6-8 Further, the influence of Kondo correlations in ultrasmall quantum dots on the thermoelectric effects was studied in Refs. 9 and 10, while the thermopower of a molecule with internal degrees of freedom and weakly coupled to the leads was discussed in Ref. 11.It is surprising that, despite the enormous interest in superconducting single-electron transistors ͑SETs͒, the thermopower of such structures has not been investigated yet. In this work we study theoretically the thermopower of a normal-superconducting-normal SET ͑NSN SET͒, i.e., a small superconducting island that is weakly coupled to normal-conducting leads ͑cf. Fig. 1͒, in an experimentally accessible regime. We show that even for rather small superconducting gaps ͑compared to the charging energy of the island͒ the functional dependence of the thermopower on the gate voltage is qualitatively changed while its amplitude remains on the same order of magnitude. This is in clear contrast to the corresponding results for the conductance w...