ThermoML—An XML-Based Approach for Storage and Exchange of Experimental and Critically Evaluated Thermophysical and Thermochemical Property Data. 4. Biomaterials

Chirico, Robert D.; Frenkel, Michael; Diky, Vladimir; Goldberg, Robert N.; Heerklotz, Heiko; Ladbury, John E.; Remeta, David P.; Dymond, J. H.; Goodwin, Anthony R. H.; Marsh, Kenneth N.; Wakeham, W. A.

doi:10.1021/je900685d

Cited by 58 publications

(83 citation statements)

References 25 publications

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“…Based on the procedure described above and using a coverage factor of k = 2 [25], while assuming the corresponding standard uncertainties given previously have a normal distribution [25], the expanded uncertainty, U x , on the mole fraction of carbon dioxide and methane in the bulk liquid phase was estimated to vary between 6.5 × 10 −4 and 8.8 × 10 −4 , and between 1.2 × 10 −4 and 1.3 × 10 −4 respectively, depending on the experimental conditions.…”

Section: Mole Fraction In the Bulk Liquid Phasementioning

confidence: 99%

CO2 and CH4 mole fraction measurements during hydrate growth in a semi-batch stirred tank reactor and its significance to kinetic modeling

Bergeron

Servio

2009

Fluid Phase Equilibria

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Section: Mole Fraction In the Bulk Liquid Phasementioning

confidence: 99%

CO2 and CH4 mole fraction measurements during hydrate growth in a semi-batch stirred tank reactor and its significance to kinetic modeling

Bergeron

Servio

2009

Fluid Phase Equilibria

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“…High pressure phase behavior data for the propoxylated neopentyl glycol diacrylate in supercritical carbon dioxide was measured, and the experimental uncertainty was estimated to be ±0.02 MPa and ±0.12 K for a given loading of the cell [15,16]. The combined expanded uncertainties of propoxylated neopentyl glycol diacrylate mole fractions were estimated to be ±0.0008 [17].…”

Section: Resultsmentioning

confidence: 99%

Phase Equilibria Measurement of Binary Mixture for the Propoxylated Neopentyl Glycol Diacrylate in Supercritical Carbon Dioxide

Byun¹

2016

Korean Chemical Engineering Research

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− Experimental data are reported on the phase equilibrium of propoxylated neopentyl glycol diacrylate in supercritical carbon dioxide. Phase equilibria data were measured in static method at a temperature of (313.2, 333.2, 353.2, 373.2 and 393.2) K and at pressures up to 27.82 MPa. At a constant pressure, the solubility of propoxylated neopentyl glycol diacrylate for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system increases as temperature increases. The (carbon dioxide + propoxylated neopentyl glycol diacrylate) system exhibits type-I phase behavior. The experimental result for the (carbon dioxide + propoxylated neopentyl glycol diacrylate) system is correlated with PengRobinson equation of state using mixing rule. The critical property of propoxylated neopentyl glycol diacrylate is predicted with Joback and Lyderson method.

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“…In this study, experimental uncertainty was evaluated as per the National Institute of Standard and Technology (NIST) protocols [4]. Few experiments were performed in triplicate and the reliability of replicated experiments was found within ± 2% having confidence interval 95%.…”

Section: Uncertainty Analysismentioning

confidence: 99%

Recovery of Glutaric Acid Using Tri-N-Butyl Phosphate: Effect of Diluents and Temperature

Athankar¹,

Wasewar²,

Varma³

et al. 2017

J Chem Eng Process Technol

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Reactive separation of glutaric acid with tri-n-butyl phosphate in ethyl acetate and hexanol was studied to explain the effect of temperature on the extraction. Extraction was carried out at different temperature range of 308-338 K. The reactive extraction results were discussed in terms of overall distribution coefficients (K D ), degree of extraction (η%), loading ratio (φ), and equilibrium complexation constants (K E ). The results showed that an increase in temperature reduced distribution coefficients and extraction efficiency for both diluent used in the organic phase. Moreover, thermodynamic function viz enthalpy (∆H), entropy (∆S) and Gibbs free energy (∆G) were calculated. Reactive extraction of glutaric acid by tri-n-butyl phosphate resulted in negative values of enthalpy. Thus, the reactive extraction process is an exothermic reaction.

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ThermoML—An XML-Based Approach for Storage and Exchange of Experimental and Critically Evaluated Thermophysical and Thermochemical Property Data. 4. Biomaterials

Cited by 58 publications

References 25 publications

CO2 and CH4 mole fraction measurements during hydrate growth in a semi-batch stirred tank reactor and its significance to kinetic modeling

CO2 and CH4 mole fraction measurements during hydrate growth in a semi-batch stirred tank reactor and its significance to kinetic modeling

Phase Equilibria Measurement of Binary Mixture for the Propoxylated Neopentyl Glycol Diacrylate in Supercritical Carbon Dioxide

Recovery of Glutaric Acid Using Tri-N-Butyl Phosphate: Effect of Diluents and Temperature

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