2010
DOI: 10.1515/znb-2010-0112
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Thermolysereaktionen der donorfreien Silanimine tBu2Si=N-SiRtBu2 (R = tBu, Ph) / Thermolysis Reactions of Donor-free Silanimines tBu2Si=N-SiRtBu2 (R = tBu, Ph)

Abstract: The donor-free silanimines tBu2Si=N-SiRtBu2 (R = tBu, Ph), which are prepared from tBu2ClSiN3 and NaSiRtBu2 at −78 ◦C inBu2O, decompose in benzene at room temperature with the formation of isobutene. Products of ene reactions of isobutene and tBu2Si=N-SiRtBu2 (R = tBu, Ph) are formed. X-Ray quality crystals of H2C=C(CH2SitBu2-NH-SiPhtBu2)2 (monoclinic, space group C2/c, Z = 4) were grown from a benzene solution at ambient temperature, whereas single crystals of H2C=C(CH2SitBu2-NH-SitBu3)2 (monoclinic, space gr… Show more

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Cited by 17 publications
(40 citation statements)
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“…Previous attempts to unitarize Higgs inflation have required the introduction of new degrees of freedom [15,16] or higher dimensional operators [17]. In the last part of this paper we note that if gravity were to exhibit asymptotic safety in the presence of the couplings which drive Higgs inflation then the models might not suffer from any unitarity issues.…”
Section: Introductionmentioning
confidence: 83%
“…Previous attempts to unitarize Higgs inflation have required the introduction of new degrees of freedom [15,16] or higher dimensional operators [17]. In the last part of this paper we note that if gravity were to exhibit asymptotic safety in the presence of the couplings which drive Higgs inflation then the models might not suffer from any unitarity issues.…”
Section: Introductionmentioning
confidence: 83%
“…[11] (see also Ref. [12]). An interesting question is whether rendering the theory supersymmetric has any impact here; but we will not address this issue in this paper.…”
Section: Introductionmentioning
confidence: 96%
“…The correction for the Higgs direction, χ = h, in the SM+S model is given in Ref. 32 and it is unchanged for the case λ S < 0. On the other hand, in the S direction the one-loop potential does change, due to the following contribution…”
Section: Coleman-weinberg Potentialmentioning
confidence: 99%
“…One of the simplest extensions of the SM comprises the addition of a massive real scalar field, neutral under the SM gauge group and symmetric under Z 2 , to play the role of DM. [4][5][6] This scalar singlet S interacts with the SM only through the Higgs portal, S 2 |H| 2 , and has a variety of implications in different contexts, including thermal production and annihilation signals, [29][30][31] inflation, [32][33][34][35][36] baryogenesis [37][38][39] and direct detection through Higgs decay. [40][41][42][43][44] Constraints from several experiments and cosmological observations have been imposed on the scalar singlet DM model.…”
Section: Introductionmentioning
confidence: 99%
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