“…These insights play a key role to improve the existing or to develop new optical devices, such as lasers, light converters, sensors, hole burning high-density memories, optical fibers, and amplifiers. K 2 LnF 5 (Ln = rare earth) crystals doped with rare earth ions are important materials for optical applications such as optical amplifiers and solid-state lasers [1] and especially they are a high energy dosimeter materials of great promise [2][3][4][5]. Recently there are many reports on optical properties of the materials, such as the K 2 YF 5 :Nd 3+ , K 2 YF 5 :Pr 3+ , K 2 YF 5 :Tm 3+ , K 2 GdF 5 :Tb 3+ , and K 2 GdF 5 :Dy 3+ crystals [1][2][3][5][6][7].…”