The evaluation of trapping parameters activation energy, frequency factor, electron's life time in traps, capture cross-section, kinetics order, etc. are the most important studies in the field of themoluminescence. The thermoluminescence (TL) properties of Pr and (Ag, Pr) doped ZnSe phosphors are studied at three uniform heating rates between the temperature of 130K and 370K after excitation by UV radiation (365 nm). Trapping parameters of these phosphors have been determined and its nature is discussed.