This work investigates the effects of various sintering conditions on phase, physical properties microstructure and thermal conductivity of Y(Ba1-x
La
x
)2Cu3O7-δ where x = 0, 0.05, 0.10, 0.15, 0.20 and 0.25 mol fraction. The sintering conditions involved the sintering temperature of 920 °C and sintering time of 6, 8, 10 and 12 h. It was found that pure phase could be obtained in the samples sintered for 6 h regardless of composition. However, small amount of BaCuO2 secondary phase was obtained at other sintering time. The relatively low density and significantly reduced grain size was obtained in the samples with high La content (e.g. x = 0.20 and 0.25) regardless of the sintering time. This showed that La addition had apparent effects on sintering ability and grain growth. Phase analysis indicated that the structure changed from orthorhombic to tetragonal when the La concentration reached 0.20 and 0.25 mol fraction. SEM images of all ceramics also indicated irregular shaped grains. The effects of variation in density, microstructure and composition on the thermal conductivity of all ceramics were also discussed in details.