Thermoelectric Performance of Hybrid Inorganic/Organic Composites Based on PEDOT:PSS/Tin(II) Oxide

Abstract

PEDOT:PSS(poly(3,4‐ethylenedioxylthiophene):poly(styrenesulfonate))‐based composites often exhibit remarkable characteristics regarding high electrical conductivity and great processability, being a suitable candidate for thermoelectric (TE) applications. To increase its performance, PEDOT:PSS is commonly blended with scarce and toxic inorganic compounds based on Se, Te or Bi. In this work we propose the use of one p‐type metal oxide semiconductor (MOs): tin(II) oxide (SnO), motivated by its abundance and low toxicity. Hybrid PEDOT:PSS/SnO composites were obtained by firstly blending Ethylene glycol (EG) with PEDOT:PSS and then by adding p‐type SnO, previously synthesized by a chemical route. The mixture was deposited via spin‐coating onto glass substrates. The Power Factor (PF) of the composites increased by a factor of 300 with the combined EG/SnO composition.