2000
DOI: 10.1103/physrevb.61.3147
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Thermodynamics of the incommensurate state inRb2WO4:The Lifshitz point in

Abstract: We consider the evolution of the phase transition from the parent hexagonal phase P 6 3 /mmc to the orthorhombic phase P mcn that occurs in several compounds of A ′ A ′′ BX 4 family as a function of the hcp lattice parameter c/a. For compounds of K 2 SO 4 type with c/a larger than the threshold value 1.26 the direct first-order transition P mcn−P 6 3 /mmc is characterized by the large entropy jump ∼ R ln 2. For compoundswith c/a < 1.26 this transition occurs via an intermediate incommensurate (Inc) phase. DSC … Show more

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Cited by 11 publications
(3 citation statements)
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“…[3, p. 59]). Their discovery triggered considerable theoretical [7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24] and experimental interest [25,26], which has continued over the years, and after a phase of somewhat reduced intensity, has regained a lot of momentum recently [27,28,29,30,31,32,33]-in particular, on the theory side [34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51].…”
Section: Introductionmentioning
confidence: 99%
“…[3, p. 59]). Their discovery triggered considerable theoretical [7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23,24] and experimental interest [25,26], which has continued over the years, and after a phase of somewhat reduced intensity, has regained a lot of momentum recently [27,28,29,30,31,32,33]-in particular, on the theory side [34,35,36,37,38,39,40,41,42,43,44,45,46,47,48,49,50,51].…”
Section: Introductionmentioning
confidence: 99%
“…Thus, in view of Hornreich's 17 original idea regarding "a new multicritical point whose critical behavior is strikingly different from any reported previously" the extension of the LP concept to a first-order phase transition 19 has nothing to do with the main feature of LP i.e., critical behavior. Despite this, attempts are being made at labeling as LPs even those points in which all three incoming transition lines are of the first order, 25 i.e., where there is no critical behavior at all.…”
Section: Discussionmentioning
confidence: 99%
“…On the other hand, another group in A2BO4-type dielectrics (group II), e.g. K2MoO4, K2WO4, Rb2MoO4, and Rb2WO4, take the monoclinic -K2MoO4 type structure (space group C2/m) at room temperature and two typical first-order anomalies were observed above room temperature by differential scanning calorimetry (DSC) measurement [5]. Furthermore, in Rb2MoO4, the existence of polymorphous structures has been confirmed at room temperature Ferroelectrics Vol.513, 67-71 (2017) 2 [6].…”
Section: Introductionmentioning
confidence: 99%