Thermodynamics of poly(dimethylsiloxane)-alkane systems by gas-liquid chromatography

Inverse gas chromatography study of the thermodynamic behaviour of thermotropic low molar mass and polymeric liquid crystalsElectronic supplementary information (ESI) available: Partial molar enthalpies, excess enthalpies, entropies and excess entropies for hydrocarbon probes in liquid crystals. See http://www.rsc.org/suppdata/cp/b2/b202173k/

“…There is a large spread of results reported in the literature. Values measured in this work agreed more closely with the higher specific retention volumes reported in more recent work 45 although there was some variation with the aromatic probes.…”

Thermodynamics of Polymer Melts Swollen with Supercritical Gases

“…The values presented in Figures [11][12][13][14] are limiting values for gas-saturated mixtures; for operations at lower (undersaturated) gas concentrations, the values of swollen volumes, isothermal compressibility, and the coefficient of thermal expansion are correspondingly closer to the those of the pure polymer.…”

Phase equilibria and diffusion coefficients in the poly(dimethylsiloxane)+n-pentane system

“…6 shows the comparison of those data with the IGC data ( Table 2) determined in this study. The pressure decay and Table 2 Experimental VLE data for PDMS + n-pentane from the inverse gas chromatography measurements Chromosorb W/AW (Restek) Chromosorb Silcoport W (Restek) [23]; × [24]; - [25]; [26]; [27]; [28]; [29]; + [30]; [31]). …”