Thermodynamics of phenyl glycidyl ether and its reactions with diphenylcarbodiimide and phenyl isocyanate with the formation of iminooxazolidine and oxazolidinone in the 0?330 K range

Быкова, Т. А.; Kiparisova, E. G.; Frenkel, Ts. M.; Fainleib, Alexander; Панкратов, В. А.

doi:10.1007/bf00961904

Cited by 3 publications

(2 citation statements)

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“…The energy of combustion was not abstracted by Pedley in either of his recent thermochemical data compilations (Pedley et al, 1986;Pedley, 1994). Agreement between the heat capacities C sat,m obtained in this research (Table 8) with those listed in Lebedev et al (1988) is excellent although the sample was only 99.3 mol% pure. Ku ¨znetsova et al (1976) measured the energy of combustion of 1,2-epoxy-3-phenoxypropane [a possible minimum of five combustions with results based on CO 2 analyses (accurate to (0.05%)].…”

Section: Discussionsupporting

confidence: 61%

“…42, No. 6, 1997 density measurements and approximately 40 boiling-point determinations found in a Beilstein search through January 1997, the only other thermochemical or thermophysical property measurements found for 1,2-epoxy-3-phenoxypropane were measurements of heat capacities (Lebedev et al, 1988) and the energy of combustion (Ku ¨znetsova et al, 1976). The energy of combustion was not abstracted by Pedley in either of his recent thermochemical data compilations (Pedley et al, 1986;Pedley, 1994).…”

Section: Discussionmentioning

confidence: 99%

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Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for 2-Aminoisobutyric Acid (2-Methylalanine), Acetic Acid, (Z)-5-Ethylidene-2-norbornene, Mesityl Oxide (4-Methyl-3-penten-2-one), 4-Methylpent-1-ene, 2,2‘-Bis(phenylthio)propane, and Glycidyl Phenyl Ether (1,2-Epoxy-3-phenoxypropane)

Steele¹,

Chirico²,

Cowell³

et al. 1997

J. Chem. Eng. Data

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The results of a study aimed at improvement of group-contribution methodology for estimation of thermodynamic properties of organic substances are reported. Specific weaknesses where particular group-contribution terms were unknown, or estimated because of lack of experimental data, are addressed by experimental studies of enthalpies of combustion in the condensed phase, vapor-pressure measurements, and differential scanning calorimetric (DSC) heat-capacity measurements. Ideal-gas enthalpies of formation of acetic acid, (Z)-5-ethylidene-2-norbornene, mesityl oxide (4-methyl-3-penten-2-one), 4-methylpent-1-ene, glycidyl phenyl ether (1,2-epoxy-3-phenoxypropane), and 2,2‘-bis(phenylthio)propane are reported. An enthalpy of formation of 2-aminoisobutyric acid (2-methylalanine) in the crystalline phase was determined. Using a literature value for the enthalpy of sublimation of 2-aminoisobutyric acid, a value for the ideal-gas enthalpy of formation was derived. An enthalpy of fusion was determined for 2,2‘-bis(phenylthio)propane. Two-phase (solid + vapor) or (liquid + vapor) heat capacities were determined from 300 K to the critical region or earlier decomposition temperature for all the compounds except acetic acid. For mesityl oxide and 4-methylpent-1-ene, critical temperatures and critical densities were determined from the DSC results and corresponding critical pressures derived from the fitting procedures. Group-additivity parameters and ring strain energies useful in the application of group-contribution correlations were derived.

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Section: Discussionsupporting

confidence: 61%

Section: Discussionmentioning

confidence: 99%

Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for 2-Aminoisobutyric Acid (2-Methylalanine), Acetic Acid, (Z)-5-Ethylidene-2-norbornene, Mesityl Oxide (4-Methyl-3-penten-2-one), 4-Methylpent-1-ene, 2,2‘-Bis(phenylthio)propane, and Glycidyl Phenyl Ether (1,2-Epoxy-3-phenoxypropane)

Steele¹,

Chirico²,

Cowell³

et al. 1997

J. Chem. Eng. Data

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Titanium(salen)‐Catalysed Synthesis of Di‐ and Trithiocarbonates from Epoxides and Carbon Disulfide

Beattie

North

2014

ChemCatChem

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The combination of a bimetallic titanium(salen) complex [Ti(salen)O]2 and either tetrabutylammonium bromide or tributylamine forms a highly active catalyst system for the reaction between epoxides and carbon disulfide to lead to di‐ and/or trithiocarbonates. Reactions can be performed at 90 °C by using just 0.5–1.0 mol % of the catalysts. The reactions proceed with the inversion of the epoxide configuration and on the basis of kinetic and spectroscopic evidence, a mechanism to account for the results is proposed.

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Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C₁− C₁₀

Acree

Chickos

2016

Journal of Physical and Chemical Reference Data

211

116

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Thermodynamics of phenyl glycidyl ether and its reactions with diphenylcarbodiimide and phenyl isocyanate with the formation of iminooxazolidine and oxazolidinone in the 0?330 K range

Cited by 3 publications

References 3 publications

Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for 2-Aminoisobutyric Acid (2-Methylalanine), Acetic Acid, (Z)-5-Ethylidene-2-norbornene, Mesityl Oxide (4-Methyl-3-penten-2-one), 4-Methylpent-1-ene, 2,2‘-Bis(phenylthio)propane, and Glycidyl Phenyl Ether (1,2-Epoxy-3-phenoxypropane)

Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for 2-Aminoisobutyric Acid (2-Methylalanine), Acetic Acid, (Z)-5-Ethylidene-2-norbornene, Mesityl Oxide (4-Methyl-3-penten-2-one), 4-Methylpent-1-ene, 2,2‘-Bis(phenylthio)propane, and Glycidyl Phenyl Ether (1,2-Epoxy-3-phenoxypropane)

Titanium(salen)‐Catalysed Synthesis of Di‐ and Trithiocarbonates from Epoxides and Carbon Disulfide

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C₁− C₁₀

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Thermodynamics of phenyl glycidyl ether and its reactions with diphenylcarbodiimide and phenyl isocyanate with the formation of iminooxazolidine and oxazolidinone in the 0?330 K range

Cited by 3 publications

References 3 publications

Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for 2-Aminoisobutyric Acid (2-Methylalanine), Acetic Acid, (Z)-5-Ethylidene-2-norbornene, Mesityl Oxide (4-Methyl-3-penten-2-one), 4-Methylpent-1-ene, 2,2‘-Bis(phenylthio)propane, and Glycidyl Phenyl Ether (1,2-Epoxy-3-phenoxypropane)

Thermodynamic Properties and Ideal-Gas Enthalpies of Formation for 2-Aminoisobutyric Acid (2-Methylalanine), Acetic Acid, (Z)-5-Ethylidene-2-norbornene, Mesityl Oxide (4-Methyl-3-penten-2-one), 4-Methylpent-1-ene, 2,2‘-Bis(phenylthio)propane, and Glycidyl Phenyl Ether (1,2-Epoxy-3-phenoxypropane)

Titanium(salen)‐Catalysed Synthesis of Di‐ and Trithiocarbonates from Epoxides and Carbon Disulfide

Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C1− C10

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Phase Transition Enthalpy Measurements of Organic and Organometallic Compounds. Sublimation, Vaporization and Fusion Enthalpies From 1880 to 2015. Part 1. C₁− C₁₀