Thermodynamics of mixtures containing p-dioxan or tetrahydrofuran 1. Excess Gibbs free energies and excess volumes

Deshpande, D. D.; Oswal, S.L.

doi:10.1016/0021-9614(75)90263-3

Cited by 60 publications

(19 citation statements)

References 11 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Solid lines, DISQUAC calculations. Dashed lines, experimental values for the heptane system calculated using data given in [95,120]: upper curve, ı11; lower curve, ı12.…”

Section: Oxaalkane + N-alkane Mixturesmentioning

confidence: 99%

Thermodynamics of mixtures containing oxaalkanes. 5. Ether+benzene, or +toluene systems

González

Fuenté

Cobos

2011

Fluid Phase Equilibria

View full text Add to dashboard Cite

“…Solid lines, DISQUAC calculations. Dashed lines, experimental values for the heptane system calculated using data given in [95,120]: upper curve, ı11; lower curve, ı12.…”

Section: Oxaalkane + N-alkane Mixturesmentioning

confidence: 99%

Thermodynamics of mixtures containing oxaalkanes. 5. Ether+benzene, or +toluene systems

González

Fuenté

Cobos

2011

Fluid Phase Equilibria

View full text Add to dashboard Cite

“…A number of workers (8)(9)(10)(11) have utilised the direct approach developed by Grunberg and Nissan (6) and Katti and Chaudri (7) to estimate the strength of interactions in binary mixtures of nonelectrolytes from viscosity data. In continuation of our work (12)(13)(14)(15) on solution properties we report in this paper the viscosity measurements for the study of molecular interactions of six binary mixtures of cyclohexane, benzene, toluene, ethylbenzene, carbon tetrachloride, and chloroform in ethyl acetate at 303.15 K.…”

Section: Materials and Solutionsmentioning

confidence: 99%

Viscosity data of binary mixtures: ethyl acetate + cyclohexane, + benzene, + toluene, + ethylbenzene + carbon tetrachloride, and + chloroform at 303.15 K

Oswal¹,

Rathnam²

1984

Can. J. Chem.

View full text Add to dashboard Cite

“…For nonaqueous solvent mixtures, data for KBIs have been accumulating. Deshpande and Oswal (1975) reported KBIs for binary mixtures of p-dioxane and THF with cyclohexane, toluene, and n-heptane. Zielkiewicz (2003aZielkiewicz ( , 2003b reported KBIs for mixed N -methylpyrrolidinone and alcohol (MeOH and EtOH) solvents.…”

Section: Preferential Solvationmentioning

confidence: 97%

Solution Properties of Inorganic Contamination in Mixed Solvents: Theory, Progress, and Limitations

Srour¹,

McDonald

2011

Critical Reviews in Environmental Science and Technology

View full text Add to dashboard Cite

Most of what is known about the environmental fate and transport of contaminants comes from studies of dilute, aqueous solutions. Theoretical and practical aspects of hydrophobic organic contaminants in aqueous mixtures of organic solvents are well developed, but relatively little attention has been paid to those situations where inorganic contaminants such as metals, water, and organic solvents occur simultaneously. The authors discuss changes in solution properties accompanying the addition of organic solvents. They review more than 500 references to available data on ion solvation, solubility, activity, acidity, pairing, and pH in electrolyte and electrolyte-free solvent mixtures and tabulate selected experimental values. Whenever available, equations developed to estimate these properties are given and their applications and limitations described. The implications of the progress in mixed-solvents solution chemistry on contaminant behavior and transport are described. Major limitations to the study of inorganic contamination in mixed solvents include the absence of complete and comprehensive data (e.g., type of ionic species, activity coefficients, solubility constants) that characterize solute and solvent properties in these mixtures and the indefinite number of possible solute and solvent combinations. The generation of models predicting such data from easily measured benchmark solute and solvent properties is a major challenge. The availability of such database and models may open the field for environmental engineers and soil scientists to study the basic chemical processes and mechanisms of metal contamination in complex multicomponent systems.

show abstract

Thermodynamics of mixtures containing p-dioxan or tetrahydrofuran 1. Excess Gibbs free energies and excess volumes

Cited by 60 publications

References 11 publications

Thermodynamics of mixtures containing oxaalkanes. 5. Ether+benzene, or +toluene systems

Thermodynamics of mixtures containing oxaalkanes. 5. Ether+benzene, or +toluene systems

Viscosity data of binary mixtures: ethyl acetate + cyclohexane, + benzene, + toluene, + ethylbenzene + carbon tetrachloride, and + chloroform at 303.15 K

Solution Properties of Inorganic Contamination in Mixed Solvents: Theory, Progress, and Limitations

Contact Info

Product

Resources

About