Thermodynamics of (ketone+amine) mixtures. Part VI. Volumetric and speed of sound data at (293.15, 298.15, and 303.15)K for (2-heptanone+dipropylamine, +dibutylamine, or +triethylamine) systems

Alonso, Iván; Mozo, Ismael; Fuenté, Isaiás García de la; González, Juan Antonio; Cobos, José Carlos

doi:10.1016/j.jct.2011.05.003

Cited by 23 publications

(2 citation statements)

References 59 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…Densities and speeds of sound of both pure liquids and of the mixtures were measured by means of a vibrating-tube densimeter and sound analyzer, Anton Paar model DSA-5000, automatically thermostated within 0.01 K. A detailed description of the calibration of the apparatus has been given in an earlier work . The repeatability of the ρ measurements is 5·10 –3 kg·m –3 , while the relative standard uncertainty of the measurements is estimated to be 0.12%.…”

Section: Methodsmentioning

confidence: 99%

Thermodynamics of Amide + Amine Mixtures. 1. Volumetric, Speed of Sound, and Refractive Index Data for N,N-Dimethylformamide + N-Propylpropan-1-amine, + N-Butylbutan-1-amine, + Butan-1-amine, or + Hexan-1-amine Systems at Several Temperatures

et al. 2016

Self Cite

View full text Add to dashboard Cite

Values of density (ρ), speed of sound (c) and refractive index (n D) for N,N-dimethylformamide (DMF) + N-propylpropan-1-amine (DPA) or + butan-1-amine (BA) mixtures at (293.15−303.15) K, and for DMF + N-butylbutan-1-amine (DBA) or hexan-1-amine (HxA) mixtures at 298.15 K are reported. Density and speed of sound measurements were conducted using a vibrating-tube densimeter and sound analyser, Anton Paar model DSA5000; refractive index values, n D values were obtained by means of a RFM970 refractometer from Bellingham+Stanley. The experimental ρ, c and n D values have been used to determine excess molar volumes, V m E, excess adiabatic compressibilities, κS E, excess speeds of sound, c E, excess thermal expansion coefficients, α p E, and excess refractive indices, n D E. This set of data shows the existence of interactions between unlike molecules and of structural effects in the mixtures under study. V m E values of solutions including linear secondary amines are lower than those of mixtures with linear primary amines. In fact, the contribution to V m E from the breaking of amine−amine interactions is larger for the latter systems. Calculations on Rao’s constant point out that there is no complex formation between the mixture components. Dispersive interactions have been analyzed by means of the molar refraction. It is shown that solutions with DPA or HxA are characterized by similar dispersive interactions and that they mainly differ by dipolar interactions.

show abstract

Section: Methodsmentioning

confidence: 99%

Thermodynamics of Amide + Amine Mixtures. 1. Volumetric, Speed of Sound, and Refractive Index Data for N,N-Dimethylformamide + N-Propylpropan-1-amine, + N-Butylbutan-1-amine, + Butan-1-amine, or + Hexan-1-amine Systems at Several Temperatures

et al. 2016

Self Cite

View full text Add to dashboard Cite

show abstract

“…Densities were obtained using a vibrating-tube densimeter and sound analyser Anton Paar DSA 5000, which is automatically thermostated within 0.01 K. The calibration procedure has been described elsewhere [31]. The relative standard uncertainty of the ρ measurements is 0.0012.…”

Section: Apparatus and Proceduresmentioning

confidence: 99%

Thermodynamics of mixtures with strongly negative deviations from Raoult's law. XV. Permittivities and refractive indices for 1-alkanol + n -hexylamine systems at (293.15–303.15) K. Application of the Kirkwood-Fröhlich model

Hevia

González

Cobos

et al. 2018

Fluid Phase Equilibria

Self Cite

View full text Add to dashboard Cite

show abstract

Thermodynamics of Amide + Amine Mixtures. 2. Volumetric, Speed of Sound and Refractive Index Data for N,N-Dimethylacetamide + N-Propylpropan-1-Amine, + N-Butylbutan-1-Amine, + Butan-1-Amine, or + Hexan-1-Amine Systems at Several Temperatures

et al. 2016

View full text Add to dashboard Cite

Thermodynamics of (ketone+amine) mixtures. Part VI. Volumetric and speed of sound data at (293.15, 298.15, and 303.15)K for (2-heptanone+dipropylamine, +dibutylamine, or +triethylamine) systems

Cited by 23 publications

References 59 publications

Thermodynamics of Amide + Amine Mixtures. 1. Volumetric, Speed of Sound, and Refractive Index Data for N,N-Dimethylformamide + N-Propylpropan-1-amine, + N-Butylbutan-1-amine, + Butan-1-amine, or + Hexan-1-amine Systems at Several Temperatures

Thermodynamics of Amide + Amine Mixtures. 1. Volumetric, Speed of Sound, and Refractive Index Data for N,N-Dimethylformamide + N-Propylpropan-1-amine, + N-Butylbutan-1-amine, + Butan-1-amine, or + Hexan-1-amine Systems at Several Temperatures

Thermodynamics of mixtures with strongly negative deviations from Raoult's law. XV. Permittivities and refractive indices for 1-alkanol + n -hexylamine systems at (293.15–303.15) K. Application of the Kirkwood-Fröhlich model

Thermodynamics of Amide + Amine Mixtures. 2. Volumetric, Speed of Sound and Refractive Index Data for N,N-Dimethylacetamide + N-Propylpropan-1-Amine, + N-Butylbutan-1-Amine, + Butan-1-Amine, or + Hexan-1-Amine Systems at Several Temperatures

Contact Info

Product

Resources

About