A simple yet accurate thermodynamic model was developed here to represent the nonideal behavior of single electrolytes in water at very high molalities and within a wide temperature range. The present model was obtained from an analytical expression of the excess Gibbs free energy (G-excess) which comprises three major contributions; in this context, a chemical term in the model handles the most predominant short-range ion− solvent interactions by means of a chemical equilibrium approach based on a stepwise ion solvation, whereas another term in the model of physical nature also contributes in describing the aforementioned interactions by incorporating a simple Margules equation, and last, a continuum-solvent term given by the explicit mean-spherical-approximation (MSA) expression serves to account for long-range ion−ion forces. The resulting G-excess model was applied to the representation of experimental mean ionic activity coefficients and osmotic coefficients of various representative aqueous electrolyte solutions: AgNO 3 , CaCl 2 , HCl, HClO 4 , HF, HNO 3 , KF, KOH, LiBr, LiCl, LiNO 3 , NaCNS, NaOH, NH 4 NO 3 , ZnBr 2 , and ZnCl 2 salts in water at 25 °C (and from 0 up to 300 °C only in the case of KOH) and at high concentrations (up to 83.263 M). The results indicated a very good agreement between the experimental data and those calculated using the present G-excess model for the majority of the electrolyte solutions considered here.