Thermodynamics of amalgam cells {M-amalgam|MCl2 (m)|AgCl|Ag} (M=Sr, Ba) and primary medium effects in {methanol+water} and {ethanol+water} solvent mixtures

Falciola, L.; Mussini, Patrizia R.; Mussini, T.; Vimercati, Alessandro

doi:10.1016/j.jct.2004.09.011

Cited by 3 publications

(1 citation statement)

References 43 publications

(57 reference statements)

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“…The Cs amalgam electrodes in the cells (I) were of the flowing dilute-amalgam type [2,15,16]. The cell design, and the electrolytic method of deposition of these amalgam electrodes by Cs deposition on a mercury cathode from aqueous 0.25 mol AE kg À1 Cs 2 CO 3 solutions were described earlier [2,15].…”

Section: Methodsmentioning

confidence: 99%

Thermodynamics of the amalgam cells {Cs-amalgam|CsX (m)|AgX|Ag} (X=Cl, Br, I) and primary medium effects in (methanol+water), (acetonitrile+water), and (1,4-dioxane+water) solvent mixtures

Falciola

Longoni

Mussini

et al. 2006

The Journal of Chemical Thermodynamics

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Section: Methodsmentioning

confidence: 99%

Thermodynamics of the amalgam cells {Cs-amalgam|CsX (m)|AgX|Ag} (X=Cl, Br, I) and primary medium effects in (methanol+water), (acetonitrile+water), and (1,4-dioxane+water) solvent mixtures

Falciola

Longoni

Mussini

et al. 2006

The Journal of Chemical Thermodynamics

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Standard, Formal, and Other Characteristic Potentials of Selected Electrode Reactions

Inzelt

2006

Encyclopedia of Electrochemistry

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The sections in this article are Group 1 Elements Group 2 Elements Group 3 Elements Group 4 Elements Group 5 Elements Group 6 Elements Group 7 Elements Group 8 Elements Group 9 Elements Group 10 Elements Group 11 Elements Group 12 Elements Group 13 Elements Group 14 Elements Group 15 Elements Group 16 Elements Group 17 Elements Group 18 Elements Acknowledgment

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Correlation and Prediction of Thermodynamic Properties of Nonaqueous Electrolytes by the Modified TCPC Model

Zhang

Guo

et al. 2007

J. Chem. Eng. Data

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In this work, the modified three-characteristic-parameter correlation model was introduced to correlate and predict the thermodynamic properties, such as the mean activity coefficient, the osmotic coefficient, and the solvent activity, of different kinds of nonaqueous electrolyte solutions. Two sets of parameters, (b, S) and (b, S, n), for 46 single salts in methanol, ethanol, and 2-propanol, etc., were regressed from literature data at 298.15 K. Results of standard deviations showed the good applicability of our model. The calculated results of the mean activity coefficient by our model and the Pitzer model have been compared with each other with good agreement. Smoothed experimental data of osmotic coefficients and solvent activities were calculated with the present model with three or two parameters, and the one with three parameters showed a better performance. We also extended this model for some nonaqueous systems at elevated temperatures, and we also found good consistency between the results calculated from our model and experimental data. Moreover, we further developed this model for calculating those in the mixed-solvent electrolyte systems. The results showed our modified model could adequately describe these complicated electrolyte solutions.

show abstract

Thermodynamics of amalgam cells {M-amalgam|MCl2 (m)|AgCl|Ag} (M=Sr, Ba) and primary medium effects in {methanol+water} and {ethanol+water} solvent mixtures

Cited by 3 publications

References 43 publications

Thermodynamics of the amalgam cells {Cs-amalgam|CsX (m)|AgX|Ag} (X=Cl, Br, I) and primary medium effects in (methanol+water), (acetonitrile+water), and (1,4-dioxane+water) solvent mixtures

Thermodynamics of the amalgam cells {Cs-amalgam|CsX (m)|AgX|Ag} (X=Cl, Br, I) and primary medium effects in (methanol+water), (acetonitrile+water), and (1,4-dioxane+water) solvent mixtures

Standard, Formal, and Other Characteristic Potentials of Selected Electrode Reactions

Correlation and Prediction of Thermodynamic Properties of Nonaqueous Electrolytes by the Modified TCPC Model

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