Thermodynamic Study of Binary Sodium Chloride and Rubidium Chloride in Mixed Methanol–Water Employing the EMF Method
Fatemeh Abbasi Rostami,
Rahman Salamat-Ahangari
Abstract:This article reports the results of thermodynamic modeling
of activity
and osmotic coefficients of the quaternary system of mixed NaCl +
RbCl in mixed CH3OH + H2O solvent based on the
potentiometric method at 298.15 ± 0.05 K. By employing the EMF
method without the liquid junction comprising chloride-selective and
sodium-selective electrodes, the measurements were accomplished over
the concentration range from 0.0005 up to 2.4941 mol·kg–1 for different series of salt molal ratios (r = m
NaCl/m
RbCl = 100,
150,… Show more
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