Abstract:Four qualitatively different thermodynamic states have been identified for hydrated sodium chlo ride ion pairs in water vapor. Two of the states are stable, and the other two are unstable. The stable states of a contact ion pair (CIP) and a solvent separated ion pair (SSIP) represent sites of heterogeneous nucleation in supersaturated vapors. The unstable states form free energy barriers that separate the stable states. As the temperature is elevated, the SSIP states become more stable than the CIP states alre… Show more
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