Thermodynamic properties of water + normal alcohols and vapor-liquid equilibria for binary systems of methanol or 2-propanol with water

Experimental vapour–liquid equilibrium data of the quaternary system Methanol (1) + Isopropyl alcohol (2) + Water (3) + Glycerol (4) along with Isopropyl alcohol (2) + Glycerol (4) and Isopropyl alcohol (2) + Water (3) binary data at atmospheric and sub-atmospheric pressures

“…In the present study, the authors found that the best-fitting model for this binary system predicts an azeotrope at the pressure studied. This is in agreement with data reported in literature [5][6][7][8]. The authors did not find any experimental data in literature for the quaternary system at the pressures reported in this work.…”

A general model for predicting the flash point of miscible mixtures

“…This study also compared the predictive capability of our proposed model with Garland and Malcolm's statistical analogue [11]. The aqueous solutions of methanol, ethanol and isopropanol are all non-ideal, and the activity coefficients corresponding to the flammable components for such solutions are all greater than unity [18][19][20]. By contrast, the binary solution of methanol + ethanol behaves almost like an ideal solution [19].…”

“…This research attempts to compare the predictive efficacy of the model for the ternary aqueous-organic solutions using binary interaction parameters obtained from a ternary or binary system. These binary interaction parameters for binary systems were adopted from different reports ( Table 2) [18][19][20][21]23].…”

The maximum flammable content for binary aqueous–organic mixtures not to flash and their maximum flash points

“…The Antoine coefficients, obtained from the literature, and the pure compound flash point data, derived from the flash point analyzer, are listed in Table . The binary interaction parameters of the NRTL, Wilson, and UNIQUAC models were adapted from the literature and listed in Table . The group volume and surface area parameters and the UNIFAC group interaction parameters for the different UNIFAC‐type models were sourced from the literature …”