Thermodynamic properties of liquid Rb-Pb alloys

Tumidajski, Peter J.; Petric, Anthony; Takenaka, Tadashi; Pelton, Arthur D.; Saboungi, M. L.

doi:10.1088/0953-8984/2/1/017

Cited by 25 publications

(20 citation statements)

References 17 publications

(17 reference statements)

Supporting

Mentioning

Contrasting

Order By: Relevance

“…The experimental apparatus and procedure has been described in previous publications (16,17). The electromotive force cell was a simple alloy concentration cell described schematically as, Bi-Na 11 P-Al2O3 11 Bi-Na/l P-A1203 11 (CuTe)-Na…”

Section: Methodsmentioning

confidence: 99%

Thermodynamic properties of the ternary Na–Cu–Te alloy by electromotive force measurements with an alumina solid electrolyte

Tumidajski¹,

Kuehler²

1990

Can. J. Chem.

View full text Add to dashboard Cite

. Can. J. Chem. 68, 247 (1990). Activity coefficients for sodium metal in the equimolar CuTe alloy were measured up to 54 at.% sodium at 913 K. The experimental technique consisted of an alloy concentration cell with a solid alumina electrolyte. The results indicated that the solutions were H e~i a n up to 1 at.% sodium. In addition, for dilute sodium concentrations, there is an exosolution effect. However, for the more concentrated solutions, there is some ionicity.

show abstract

Section: Methodsmentioning

confidence: 99%

Thermodynamic properties of the ternary Na–Cu–Te alloy by electromotive force measurements with an alumina solid electrolyte

Tumidajski¹,

Kuehler²

1990

Can. J. Chem.

View full text Add to dashboard Cite

show abstract

“…Included in Fig. 3 are results for the Rb-Pb system reported earlier (2). There are several interesting features.…”

Section: Fig 4 Variation Ofmentioning

confidence: 67%

“…[2] rearranged to, Figure 3 shows the compositional dependence of In yRb at 606°C (879 K) for the Rb-Pb-Sn alloys. Included in Fig.…”

Section: Fig 4 Variation Ofmentioning

confidence: 99%

Thermodynamic investigation of the ternary K–Pb–Sn and Rb–Pb–Sn alloys

Tumidajski¹

1991

Can. J. Chem.

View full text Add to dashboard Cite

PETER J. TUMIDAJSKI. Can. J. Chem. 69, 458 (1991). Activity coefficients for alkali metals in the K-Pb-Sn and Rb-Pb-Sn alloys were measured at 606°C (879 K) for compositions generally less than about 10 at.% alkali metal. An alkali metal concentration cell with a potassium or rubidium substituted P-A1203 solid electrolyte was used to perform the experiments. A coulometric titration technique was used to electrochemically generate the alkali metal in the Pb-Sn alloys. The results indicated that, for both potassium and rubidium alloys, as solvent composition is varied from pure tin to pure lead the liquid becomes more associated, suggesting the formation of complex species.Key words: thermodynamics, alkali metals, liquid alloys.

show abstract

“…Invited Paper for the 5th International Conference on Structure of Non-Crystalline Materials, Sendai, Japan, Sept. [2][3][4][5][6]1991 This work is supported by the U.S. Department of Energy, Basic Energy Sciences, Materials Sciences, under contract No. W-31-109-ENG-38.…”

Section: /Smmentioning

confidence: 99%