Thermodynamic properties of deuterium oxide in the temperature range from 6 to 350K

Смирнова, Н. Н.; Быкова, Т. А.; Durme, Kurt Van; Mele, Bruno Van

doi:10.1016/j.jct.2005.09.005

Cited by 21 publications

(31 citation statements)

References 18 publications

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“…The freezing point for D2O is 3.7 ˚C, 40 which suggests that upon freezing D2O solutions the D2O crystallizes first, while any H2O impurity remains unfrozen initially, allowing it to preferentially partition into LLRs. The net result would be a reduction of the expected D2O enhancement because of preferential H2O contamination in LLRs.…”

Section: Diagnostic Tests For 1 O2* On Illuminated Icementioning

confidence: 99%

Degradation of organic pollutants in/on snow and ice by singlet molecular oxygen (¹O*2) and an organic triplet excited state

Bower

Anastasio

2014

Environ. Sci.: Processes Impacts

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Section: Diagnostic Tests For 1 O2* On Illuminated Icementioning

confidence: 99%

Degradation of organic pollutants in/on snow and ice by singlet molecular oxygen (¹O*2) and an organic triplet excited state

Bower

Anastasio

2014

Environ. Sci.: Processes Impacts

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“…The values of C p L calculated from the expressions of P sat given by Kraus and Greer, 6 Jones, 4 Pupezin et al, 1 Bottomley, 5 Hill and MacMillan, 16 Harvey and Lemmon, 17 Matsunaga and Nagashima, 18 21 Braibanti et al, 22 Rivkin and Egorov, 24 and Smirnova et al 23 in the range from the triple point to 335 K. But the SRT analytical expression is agreeable with the measured values which have less than 1 % variation as indicated in Figure 9. Below the triple point, the two groups of measurements of C p L reported by Angell et al, 25 one was read from the bulk samples, and another was obtained from the emulsion samples.…”

Section: Pmentioning

confidence: 99%

Thermal Properties of Deuterium Oxide near the Triple Point Predicted from Nonequilibrium Evaporation

Duan

Crivoi

2010

J. Chem. Eng. Data

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Statistical rate theory (SRT) was applied to predict the saturation pressure of D 2 O numerically near the triple point based on the interfacial liquid-phase temperature, the interfacial vapor-phase temperature, and the local evaporation flux from 102 local measures in a series of nonequilibrium steady-state droplet evaporation experiments. An analytical expression of the saturation pressure, P sat , was obtained from the predicted values. Following the thermodynamic relations, the specific entropy of evaporation, h fg , and the liquid-phase specific heat at constant pressure, C p L , were computed. The agreement that the calculated values of these properties with those obtained from the independent measurements indicates that the SRT expression accurately predicts the thermal properties of D 2 O near the triple point.

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“…However, these interpretations are misleading since the electronic-correlation-degree α w determined via x-ray is, in actual fact, different in nature from the coordination degree derived from C pwh . [21]. This value reveals correlations outside the bounds of the equipartition theorem (see below).…”

mentioning

confidence: 91%

The quantum phase-transitions of water

Fillaux

2017

EPL

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It is shown that hexagonal ices and steam are macroscopically quantum condensates, with continuous spacetime-translation symmetry, whereas liquid water is a quantum fluid with broken time-translation symmetry. Fusion and vaporization are quantum phase-transitions. The heat capacities, the latent heats, the phase-transition temperatures, the critical temperature, the molar volume expansion of ice relative to water, as well as neutron scattering data and dielectric measurements are explained. The phase-transition mechanisms along with the key role of quantum interferences and that of Hartley-Shannon's entropy are enlightened. The notions of chemical bond and force-field are questioned. 66 perature probed via projective measurements. It is differ-67 ent in nature, but not necessarily different in value, from 68 the thermodynamic temperature of the surroundings, T. 69 At thermal equilibrium, the condensate is stable, that is 70 immune to decoherence, as long as E is lower than the 71 Helmholtz energy of the statistical analogue [10]. There is 72 no upper limit in temperature, insofar as the continuous 73 spacetime translation symmetry is preserved. 74 At the microscopic level, an incoming wave breaking 75 the continuous translation-symmetry realizes a transitory 76 state that is not an eigenstate of the condensate. The 77 condensate as a whole is virtually unaffected by a single 78 event and spontaneous decay of the induced instability de-79 stroys quantum correlations with the outgoing wave. The 80 condensate is, therefore, immune to decoherence induced 81 by a measurement, or by the environment. As long as 82 the probability for an incoming wave to entangle with a 83 state previously realized is insignificant, the outcome of 84 a measurement is independent of previous events. Every 85 single realization can be projected onto the eigenstates 86 of a context-dependent operator. On the one hand, the 87 outcome of elastic scattering events breaking the continu-88 ous space-translation symmetry yields the static probabil-89 ity densities in the "x-space" of the nuclear coordinates, 90 while the time variable and the vibrational states remain 91 indefinite. On the other hand, energy transfer breaking 92 the time-translation symmetry realizes eigenstates of the 93

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Thermodynamic properties of deuterium oxide in the temperature range from 6 to 350K

Cited by 21 publications

References 18 publications

Degradation of organic pollutants in/on snow and ice by singlet molecular oxygen (¹O*2) and an organic triplet excited state

Degradation of organic pollutants in/on snow and ice by singlet molecular oxygen (¹O*2) and an organic triplet excited state

Thermal Properties of Deuterium Oxide near the Triple Point Predicted from Nonequilibrium Evaporation

The quantum phase-transitions of water

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Thermodynamic properties of deuterium oxide in the temperature range from 6 to 350K

Cited by 21 publications

References 18 publications

Degradation of organic pollutants in/on snow and ice by singlet molecular oxygen (1O*2) and an organic triplet excited state

Degradation of organic pollutants in/on snow and ice by singlet molecular oxygen (1O*2) and an organic triplet excited state

Thermal Properties of Deuterium Oxide near the Triple Point Predicted from Nonequilibrium Evaporation

The quantum phase-transitions of water

Contact Info

Product

Resources

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Degradation of organic pollutants in/on snow and ice by singlet molecular oxygen (¹O*2) and an organic triplet excited state

Degradation of organic pollutants in/on snow and ice by singlet molecular oxygen (¹O*2) and an organic triplet excited state