Thermodynamic properties of chiral fenchones in some solutions at T=298.15K

Excess molar enthalpies of R-fenchone+propan-1-ol or +propan-2-ol. Modeling with COSMO-RS and UNIFAC

“…Their description can be found in table 1. A comparison between experimental and literature data [13][14][15][16] of pure propan-1-ol, propan-2-ol and fenchone is reported in table 2. It can be observed that there is a good agreement between both sets of values.…”

Enthalpic discrimination of R‐ and S‐limonenes in nonpolar solvents at 298.15 K

“…Thermodynamic discrimination of chiral compounds is one of the most interesting goals in solution chemistry and previous studies have been conducted in this field 1–5. To clarify chiral discrimination, the interactions of 38 hetero‐chiral compounds systems were reported by calorimetry 6–16. All observed systems showed a very small enthalpy change over the entire range of mole fractions.…”