Thermodynamic properties of aqueous mixtures of hydrophilic compounds 2. Aminoethanol and its methyl derivatives

Touhara, Hidekazu; Okazaki, Susumu; Okino, Fumito; Tanaka, Hideki; Ikari, Kenji; Nakanishi, Kochiro

doi:10.1016/0021-9614(82)90026-x

Cited by 110 publications

(90 citation statements)

References 10 publications

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“…Indeed, the standard hydration enthalpy of an aliphatic -NH, group is approximately 3 kJ mol-' more exothermic than that of an -OH group (21). This interpretation is also supported by the observation of less negative AGE, values in aqueous mixtures of N-methyl-2-aminoethanol and N,N-dimethyl-2-aminoethanol (14).…”

Section: Resultssupporting

confidence: 55%

“…or EA infinitely diluted in water, are collected in Tables 3 Molar functions (x;j and 4 and compared with available literature data (13)(14)(15)(16)(17)(18).…”

Section: Resultsmentioning

confidence: 99%

“…Consequently, from these macroscopic measures of molecular interactions in the W-EA and W-EG systems, one would expect their 'calculated from eqs. [12]- [14] and data from refs. 14 and 20.…”

Section: Resultsmentioning

confidence: 99%

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A comprehensive thermodynamic investigation of water–ethanolamine mixtures at 10, 25, and 40 °C

Pagé¹,

Huot²,

Jolicoeur³

1993

Can. J. Chem.

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. The density, isobaric specific heat capacity, and isentropic compressibility of water-ethanolamine (W-EA) mixtures have been measured at three temperatures (10, 25, and 40°C) over the entire composition range. The results were used to calculate various thermodynamic excess functions of these mixtures, namely: the excess molar volume (v:), excess molar isentropic and isothermal compressibilities ( K : . , , K:,,), excess molar isobaric and isochoric heat capacities (CF,,,,, CB,,,), and excess molar isobaric expansion (aVt/aT),. The corresponding partial molar quantities for ethanolamine in the mixtures were also computed. These excess and partial molar quantities were compared with those observed earlier in the water -ethylene glycol (W-EG) (1) and in the water-2-methoxyethanol (W-ME) (2) mixtures. The similarities and differences in the properties of these systems are interpreted on the basis of the specific molecular features of the cosolvents and the concepts of cooperative fluctuations and hydrogen-bonding connectivity in liquid water and dilute aqueous solutions. [Traduit par la redaction]

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Section: Resultssupporting

confidence: 55%

“…or EA infinitely diluted in water, are collected in Tables 3 Molar functions (x;j and 4 and compared with available literature data (13)(14)(15)(16)(17)(18).…”

Section: Resultsmentioning

confidence: 99%

See 1 more Smart Citation

A comprehensive thermodynamic investigation of water–ethanolamine mixtures at 10, 25, and 40 °C

Pagé¹,

Huot²,

Jolicoeur³

1993

Can. J. Chem.

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“…Leibush and Shorina [18] Conners [19] Lychkin et al [20] Danilov et al [21] Wohland [22] de Oliveira et al [23] Touhara et al [24] Nath and Bender [25] Buslaeva et al [26] Lenard et al [27] Kim et al [28] Kling and Maurer [29] Chang et al [30] Dohnal et al [31] Posey [32] Cai et al [33] Maham et al [34] Park and Lee [35] Tochigi et al [36] Tanaka et al [37] …”

Section: Regression Proceduresmentioning

confidence: 99%

The Use of the Multiobjective Function-De Algorithm in the Application of Extended UNIQUAC for CO2-MEA-H2O System

Kamalpour¹,

Mehablia²

2012

J Thermodyn Catal

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“…The physicochemical properties, thermochemical ones in particular, of TELA and related compounds in aqueous solutions have not been extensively studied (3)(4)(5)(6)(7).…”

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confidence: 99%

Solute–solute–solvent interactions in aqueous solutions of triethanolamine and dimethylsulfoxide. Microcalorimetric study

Borghesani¹,

Pulidori²

1984

Can. J. Chem.

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GIANNA BORCHESANI and FERNANDO PULIDORI. Can. J. Chem. 62, 2898 (1984).The heats of dilution of aqueous solutions of triethanolamine (TELA) and dimethylsulfoxide (DMSO) were determined up to -3 mol kg-', at 25'C.The various enthalpic pair and triplet interaction coefficients, h,,, h,,,, have been evaluated from the data. The h,, for both TELA and DMSO are positive and indicate a prevailing hydrophobic character of TELA and DMSO interactions in highly dilute aqueous solutions.The triplet coefficients are small and negative for both compounds. Dipolar interactions and normal solvation through H-bonding seem to be more important than the size or the solvophobic effect in determining the triplet enthalpic coefficients.GIANNA BORCHESANI et FERNANDO PULIDORI. Can. J. Chem. 62, 2898Chem. 62, (1984.Operant a 25°C et h des concentrations allant jusqu'h environ 3 mollkg, on a dCterminC les chaleurs de dilution de solutions aqueuses de trikthanolamine (TELA) et de dimCthylsulfoxyde (DMSO).Utilisant ces donnCes, on a tvalut les divers coefficients, h,, et h,,,, d'interaction enthalpique. Les valeurs de h,, tant pour la TELA que pour le DMSO sont positives; ces rtsultats indiquent que, en solutions aqueuses trks diludes, les interactions de la TELA et du DMSO ont un caractkre predominant qui est hydrophobe.Pour chacun des composts, les coefficients triplets sont petits et nkgatifs. Les interactions dipolaires et la solvatation normale par le biais de liaisons hydrogttnes semblent donc des facteurs plus importants que la taille ou l'effet solvophobe dans la dttermination des coefficients enthalpiques triplets.[Traduit par le journal]Triethanolamine (TELA) and dimethylsulfoxide (DMSO) belong to different classes of polar organic compounds which are miscible with water in any proportion. Whereas TELA, often defined as a highly hydrophilic substance, is polyfunctional in its interactions with water, DMSO is controversially defined (1, 2) and is only capable of acting as an H-acceptor in H-bonding with water.The physicochemical properties, thermochemical ones in particular, of TELA and related compounds in aqueous solutions have not been extensively studied (3-7).On the contrary, extensive studies have been performed on the therrnochemical properties (1, 8-13) as well as other thermodynamic properties (14, 15) of DMSO-H20 mixtures. Some of the works quoted, together with spectroscopic evidence of various nature (6,8,12,(16)(17)(18)(19), underline the formation of H-bonded DMSO-H,O complexes. Cautious and more in depth analysis (1 1, 19) points out the possibility of different kinds of interactions between DMSO and water in different concentration regions. However, although some peculiarities of the above mentioned systems can be deduced from the analysis of the physicochemical properties over the whole composition range, the relationships between these properties, excess ones in particular, and composition are rather complicated, especially for sufficiently high organic concentrations. Thus from these rela-. tionships it i s di...

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Thermodynamic properties of aqueous mixtures of hydrophilic compounds 2. Aminoethanol and its methyl derivatives

Cited by 110 publications

References 10 publications

A comprehensive thermodynamic investigation of water–ethanolamine mixtures at 10, 25, and 40 °C

A comprehensive thermodynamic investigation of water–ethanolamine mixtures at 10, 25, and 40 °C

The Use of the Multiobjective Function-De Algorithm in the Application of Extended UNIQUAC for CO2-MEA-H2O System

Solute–solute–solvent interactions in aqueous solutions of triethanolamine and dimethylsulfoxide. Microcalorimetric study

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