Physical Chemistry of Organic Solvent Systems 1973
DOI: 10.1007/978-1-4684-1959-7_2
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Thermodynamic Measurements

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Cited by 9 publications
(14 citation statements)
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“…We have decided to use methanol for this purpose. The Δ t X ° ( X = G , H , S ) of cations from MeOH to any other solvent (e.g., EtOH) were obtained by combining the corresponding functions of transfer from water: The data, based on Ph 4 AsPh 4 B convention, were taken from refs and . Transfer thermodynamic parameters for M L + were calculated using the following expression: Such analysis resulted, for example, in the thermodynamic cycle shown in Scheme , which explains differences in standard reaction Gibbs energies for the binding of Na + in MeOH and EtOH.…”
Section: Discussionmentioning
confidence: 99%
See 1 more Smart Citation
“…We have decided to use methanol for this purpose. The Δ t X ° ( X = G , H , S ) of cations from MeOH to any other solvent (e.g., EtOH) were obtained by combining the corresponding functions of transfer from water: The data, based on Ph 4 AsPh 4 B convention, were taken from refs and . Transfer thermodynamic parameters for M L + were calculated using the following expression: Such analysis resulted, for example, in the thermodynamic cycle shown in Scheme , which explains differences in standard reaction Gibbs energies for the binding of Na + in MeOH and EtOH.…”
Section: Discussionmentioning
confidence: 99%
“…The transfer of Na + from MeOH to NMF is favorable in terms of both enthalpy and entropy (Δ t H ° (Na + , MeOH → NMF) = −9 kJ mol –1 ; Δ t S ° (Na + , MeOH → NMF) = 21 J K –1 mol –1 , Schemes S5 and S6). , …”
Section: Discussionmentioning
confidence: 99%
“…Previous studies (9,22) indicated apparent deviation of the concentrations of adenine nucleotides in the ascites tumor cell from the adenylate kinase equilibrium when the energy state of the cell is high, although in all other metabolic states total adenine nucleotides appear to be in equilibrium (9,10,22 Table 2. The extent of deviation of the mass action ratios from the corresponding equilibrium values increased from 3.5-fold to 11-fold when the MgATP or total ATP levels were nearly doubled by incubation of the cells with adenosine, Pi, and Mg2+.…”
Section: Resultsmentioning
confidence: 99%
“…The values of the free energies of transfer of ions from one solvent to another are reliable in view of the compensation of the ~d-/0 and TZarS O terms, where the structural contributions of unknown magnitudes largely cancel out [5].…”
Section: ~Go(ion) = Ago(neut) + Ago(el)(ion)mentioning
confidence: 99%
“…Though a number of theoretical and semi-empirical extrathermodynamic methods have been attempted to divide the free energies of transfer into single-ion contributions, all the methods have some inherent limitations and the results obtained are usually divergent [1][2][3][4][5].…”
mentioning
confidence: 99%