2012
DOI: 10.1002/srin.201100202
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Thermodynamic Calculation and Experimental Investigation of Second Phase Particles in Low Carbon Nb Microalloyed Steels

Abstract: Many experimental methods such as transmission electron microscopy (TEM) and X-ray energy dispersive spectroscopy were used to study the precipitates of low carbon steel with niobium addition, the austenite/carbonitride equilibrium in Fe-Nb-C-N system was performed in this paper. The equilibrium volume fraction, chemical driving force of carbonitride precipitation fraction of each element in austenite, and carbonitride at different temperature were calculated. The results show that the equilibrium mole fractio… Show more

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Cited by 6 publications
(6 citation statements)
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“…The atom fraction of C and Nb decreases. There is ample experimental evidence18, 19 to show that Nb‐rich particles are more likely to be found with decreasing temperature and Ti‐rich particles exist at elevated temperature. The computed result presents good agreements with experimental observations.…”
Section: Resultsmentioning
confidence: 99%
“…The atom fraction of C and Nb decreases. There is ample experimental evidence18, 19 to show that Nb‐rich particles are more likely to be found with decreasing temperature and Ti‐rich particles exist at elevated temperature. The computed result presents good agreements with experimental observations.…”
Section: Resultsmentioning
confidence: 99%
“…The solubility products are ${lg} K_{[{\rm M}][{\rm X}]}^{{\rm wt}\%} = A- B/T$ , where A and B are constants, [M] and [X] are the concentrations of the respective species in solution as listed in Table 2. But in the equations the concentrations and solubility products are expressed by molar fraction, thus, the following expression is used, where A and B are the tabulated parameters for each precipitate11, X % is the content of carbon or nitrogen, and M % is the content of microalloying element.…”
Section: Discussionmentioning
confidence: 99%
“…It is well recognized that the composition, size, distribution, and volume fraction of the second phase particles controlled by the thermodynamic equilibrium contribute largely to controlling and improving the microstructure and mechanical properties of the steel products [13][14][15][16][17]. The thermodynamic and kinetic analysis of the solid solution and precipitation behavior of the microalloying elements in steel, as well as modeling and simulation, have been studied by researchers for many years [18][19][20]. Han et al [7] investigated the precipitation behavior of Ti in low C medium manganese steel treated by various processes and discovered that the dislocation strengthening mechanism induced by TiC precipitation is dominant for the variation of both strength and toughness.…”
Section: Introductionmentioning
confidence: 99%