2006
DOI: 10.1016/j.ijhydene.2005.04.004
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Thermodynamic analysis of ethanol/water system with the stoichiometric method

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Cited by 128 publications
(86 citation statements)
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“…As shown by equilibrium calculations (for example, [43,44], for two different methodologies) a sufficient loading of a catalyst with the correct selectivity towards the reforming can eliminate any byproduct (except methane) when working at the proper temperature.…”
Section: Esr: Conversion Rates and Steady Statesmentioning
confidence: 99%
“…As shown by equilibrium calculations (for example, [43,44], for two different methodologies) a sufficient loading of a catalyst with the correct selectivity towards the reforming can eliminate any byproduct (except methane) when working at the proper temperature.…”
Section: Esr: Conversion Rates and Steady Statesmentioning
confidence: 99%
“…Thermodynamic analysis shows that coke production, with graphite structure, is unfavorable when the water to ethanol ratio is equal to three, at temperatures exceeding 227e277 C [35]. In the present work, however, coke formation may be related to the production of a disordered carbonaceous structure instead of graphite one.…”
Section: Catalysts Evaluationmentioning
confidence: 49%
“…In the present work, however, coke formation may be related to the production of a disordered carbonaceous structure instead of graphite one. Moreover, the thermodynamic analysis cannot predict the composition inside reactor when the system is far from equilibrium [35]. We can see that the lowest amount of coke was deposited on the RA and RM samples, which showed the same amount, the RAM sample showed higher amounts.…”
Section: Catalysts Evaluationmentioning
confidence: 88%
“…While the steam reforming of ethanol provides high hydrogen yields, it is a highly endothermic reaction and thus high operation temperatures are necessary. However, many other reactions can occur simultaneously with hydrogen production reactions [55,56]. Some of these result in the formation of undesirable products.…”
Section: Reaction Schemementioning
confidence: 99%