Thermochemistry of solution, solvation and hydrogen bonding of linear and cyclic ethers in solvents

Rakipov, Ilnaz T.; Semenov, Konstantin N.; Petrov, Аrtem А.; Akhmadiyarov, Aydar A.; Khachatrian, Artashes A.; Fakhurtdinova, Aliya R.; Solomonov, Boris N.

doi:10.1016/j.tca.2021.178932

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Diglyme Configuration and Apparent Ligand Cross-linking1

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“…The strong hydrogen-bond acceptor ability of diglyme is well-documented. 59 Attraction between CH 2 moieties within PET and diglyme is evident from our 1 H-1 H NMR spectral data. Furthermore, the difference in formulation between mass spectrometry and TGA suggests that at least two configurations of diglyme with significantly different binding strengths are at play.…”

Section: Diglyme Configuration and Apparent Ligand Cross-linkingmentioning

confidence: 70%