Thermochemistry of Solid‐State Formation, Structure, Optical, and Luminescent Properties of Complex Oxides Eu2MeO6 (Me–Mo, W), Eu2W2O9: A Combined Experimental and DFT Study
Yulia V. Seredina,
Aleksandr S. Oreshonkov,
Maxim S. Molokeev
et al.
Abstract:Complex oxides Eu2MeO6 (Me – Mo, W), Eu2W2O9 were obtained by a solid‐phase reaction between binary oxides. The thermodynamic and kinetic mechanisms of the reaction processes were established using a variety of physical‐chemical methods. All compounds obtained in this work crystallize in the low‐symmetry monoclinic system, forming complex framework structures, which determine a set of very valuable physical‐chemical properties. Comparison of experimental Kubelka‐Munk functions and DFT‐ calculated absorption sp… Show more
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