Thermochemistry of pentacarbonyl(2-propenyl) manganese and tetracarbonyl(η3-2-propenyl) manganese. Thermochemical considerations in alkenyl isomerisation reactions

Addison, Susan J.; Connor, Joseph A.; Kincaid, John A.

doi:10.1016/s0022-328x(97)00031-4

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Cited by 3 publications

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“…The latter value of DH z compares well indeed with the activation enthalpies of ca. 25 kcal/mol determined experimentally for the de-carbonylative conversion of a series (h 1 -allyl)Mn(CO) 5 substrates into (h 3 -allyl)Mn(CO) 4 products in decalin, which was furthermore poised as irreversible by Basolo and Palmer [35,36]. Transition state TS2 (Fig.…”

Section: Reaction Profilementioning

confidence: 94%

Synthesis of a 2-benzocymantrenylpyridine and further mechanistic insights

Djukic

Iali

Hijazi

et al. 2011

Journal of Organometallic Chemistry

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Section: Reaction Profilementioning

confidence: 94%

Synthesis of a 2-benzocymantrenylpyridine and further mechanistic insights

Djukic

Iali

Hijazi

et al. 2011

Journal of Organometallic Chemistry

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Energetics of Organomanganese Compounds

Liebman

Slayden

2011

Patai's Chemistry of Functional Groups

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Diverse aspects of the energetics of organomanganese compounds are considered in this chapter. Bond energies, enthalpies of formation and enthalpies of reaction are discussed. Classical combustion calorimetry plays only a small role compared to reaction calorimetry and techniques from contemporary ion energetics. While carbonyl, cyano, cyclopentadienyl, and benzene derivatives dominate the discussion, species with numerous other σ and/or π‐bonded ligands also appear. Quantitation is given whenever possible.

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