Thermochemical conversion of eggshell as biological waste and its application as a functional material for lithium-ion batteries

Senthil, Chenrayan; Vediappan, Kumaran; Nanthagopal, Murugan; Kang, Hyeong Seop; Santhoshkumar, P.; Gnanamuthu, R. M.; Lee, Chang Woo

doi:10.1016/j.cej.2019.04.171

Cited by 51 publications

(20 citation statements)

References 47 publications

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“…A 3D-printed biological reactive device was developed based on the selective permeability of eggshell membranes [40]. Eggshells as additive or coating agents for electrode materials prevent electrodes from contacting the electrolyte directly [41]. Biochar prepared by directly mixing eggshells with mushroom residues can effectively adsorb phosphorus and is important for reclaiming elements from sewage [42].…”

Section: Methodsmentioning

confidence: 99%

Research on High- and Low-Temperature Characteristics of Bitumen Blended with Waste Eggshell Powder

Wang

Zhang

et al. 2021

Materials

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The sustainability of resources is presently a major global concern. Sustainable construction materials can be produced by applying biological waste to engineering. Eggshells, as biological waste, are usually dumped in landfills or discarded. This causes many environmental problems including malodor, noise pollution, and serious waste of resources. To solve these problems, this study combined eggshell waste with bitumen materials for bio-roads construction. This paper investigated the impact of biological waste eggshell powder on the high- and low-temperature characteristics of bitumen materials. Scanning electron microscopy (SEM) revealed the microstructure of eggshell powder. The interaction between eggshell powder and asphalt was analyzed using Fourier transform infrared spectroscopy (FT-IR). The high- and low-temperature characteristics were investigated using conventional performance tests, and dynamic shear rheometer (DSR) and bending beam rheometer (BBR) experiments. These results indicate that eggshell powder (1) has a rough and porous microstructure; (2) has no apparent chemical reaction with asphalt; and (3) improves the consistency, hardness, and high-temperature characteristics. However, it reduces the plastic deformation capacity of asphalt, and the low-temperature crack resistance of asphalt cannot be improved. The research demonstrated that the application of eggshell powder in asphalt is feasible and has long-term resource and environmental advantages.

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Section: Methodsmentioning

confidence: 99%

Research on High- and Low-Temperature Characteristics of Bitumen Blended with Waste Eggshell Powder

Wang

Zhang

et al. 2021

Materials

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“…The works on bioceramics preparation and the preparation of nano-eggshell dominate. Nevertheless, some new application spheres have emerged, e.g., biogas production (Sari et al, 2020 ), filtration (Seeharaj et al, 2019 ), dentistry (Onwubu et al, 2019a , b ), and electrochemistry (Cherdchom et al, 2019 ; Senthil et al, 2019 ; Karuppiah et al, 2020 ). A reference to the study using ball milling of eggshell for the application in catalysis (Mosaddegh and Hassankhani, 2014 ) has been already mentioned earlier.…”

Section: Using Tools Of Mechanochemistry To Boost the Application Potmentioning

confidence: 99%

“…In their latest work, Minakshi et al fabricated a hybrid device comprising eggshellderived CaO as a capacitor anode and NiO/Co 3 O 4 as a pseudocapacitor cathode with enhanced energy density up to 35 = W h kg −1 (Minakshi et al, 2020). Also, eggshell was utilized as an inexpensive Ca 2+ (Foruzin et al, 2020) and CaO (Senthil et al, 2019) chemical source for the doping and coating of active electrode materials.…”

Section: Application Of Eggshell-based Materials In Electrochemistrymentioning

confidence: 99%

State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry

Baláž

Болдырева

Rybin

et al. 2021

Front. Bioeng. Biotechnol.

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Eggshell waste is among the most abundant waste materials coming from food processing technologies. Despite the unique properties that both its components (eggshell, ES, and eggshell membrane, ESM) possess, it is very often discarded without further use. This review article aims to summarize the recent reports utilizing eggshell waste for very diverse purposes, stressing the need to use a mechanochemical approach to broaden its applications. The most studied field with regards to the potential use of eggshell waste is catalysis. Upon proper treatment, it can be used for turning waste oils into biodiesel and moreover, the catalytic effect of eggshell-based material in organic synthesis is also very beneficial. In inorganic chemistry, the eggshell membrane is very often used as a templating agent for nanoparticles production. Such composites are suitable for application in photocatalysis. These bionanocomposites are also capable of heavy metal ions reduction and can be also used for the ozonation process. The eggshell and its membrane are applicable in electrochemistry as well. Due to the high protein content and the presence of functional groups on the surface, ESM can be easily converted to a high-performance electrode material. Finally, both ES and ESM are suitable for medical applications, as the former can be used as an inexpensive Ca2+ source for the development of medications, particles for drug delivery, organic matrix/mineral nanocomposites as potential tissue scaffolds, food supplements and the latter for the treatment of joint diseases, in reparative medicine and vascular graft producing. For the majority of the above-mentioned applications, the pretreatment of the eggshell waste is necessary. Among other options, the mechanochemical pretreatment has found an inevitable place. Since the publication of the last review paper devoted to the mechanochemical treatment of eggshell waste, a few new works have appeared, which are reviewed here to underline the sustainable character of the proposed methodology. The mechanochemical treatment of eggshell is capable of producing the nanoscale material which can be further used for bioceramics synthesis, dehalogenation processes, wastewater treatment, preparation of hydrophobic filters, lithium-ion batteries, dental materials, and in the building industry as cement.

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“…1(c-f), the double splitting of the (006/102) and (008/110) peaks appeared in all of the samples matches with the layer structure and increasing the amount of coating material does not affect the layered structure of NCM811. [36][37][38] The FT-IR spectra of the bare and LaFeO 3 -coated NCM811 electrode materials are shown in Fig. 2(a).…”

Section: Structural and Chemical Characterizationsmentioning

confidence: 99%

Surface modification of Ni-rich LiNi_0.8Co_0.1Mn_0.1O₂ with perovskite LaFeO₃ for high voltage cathode materials

et al. 2021

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Thermochemical conversion of eggshell as biological waste and its application as a functional material for lithium-ion batteries

Cited by 51 publications

References 47 publications

Research on High- and Low-Temperature Characteristics of Bitumen Blended with Waste Eggshell Powder

Research on High- and Low-Temperature Characteristics of Bitumen Blended with Waste Eggshell Powder

State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry

Surface modification of Ni-rich LiNi_0.8Co_0.1Mn_0.1O₂ with perovskite LaFeO₃ for high voltage cathode materials

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Thermochemical conversion of eggshell as biological waste and its application as a functional material for lithium-ion batteries

Cited by 51 publications

References 47 publications

Research on High- and Low-Temperature Characteristics of Bitumen Blended with Waste Eggshell Powder

Research on High- and Low-Temperature Characteristics of Bitumen Blended with Waste Eggshell Powder

State-of-the-Art of Eggshell Waste in Materials Science: Recent Advances in Catalysis, Pharmaceutical Applications, and Mechanochemistry

Surface modification of Ni-rich LiNi0.8Co0.1Mn0.1O2 with perovskite LaFeO3 for high voltage cathode materials

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Surface modification of Ni-rich LiNi_0.8Co_0.1Mn_0.1O₂ with perovskite LaFeO₃ for high voltage cathode materials