Thermoanalytical investigations about the metal–amino acid interactions

Farias, Robson Fernandes de; Júnior, Hélio Scatena; Airoldi, Cláudio

doi:10.1016/s0162-0134(99)00023-9

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Gly Zn(gly) 2 and Complex (1)1

Introduction1

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2002

2015

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Cited by 26 publications

(2 citation statements)

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“…2). However, de Farias et al [43] detected a similar decrease (124 cm −1 ) in the case of CdCl 2 .2Gly and predicted a carboxylate coordination only through the carboxylate. Similarly, value ( = 171) decreases in [Zn(N-Boc-gly) 2 ] complex [44].…”

Section: Gly Zn(gly) 2 and Complex (1)mentioning

confidence: 79%

Utilization of IR spectral detailed analysis for coordination mode determination in novel Zn–cyclen–aminoacid complexes

Vargová

Almáši

Arabuli

et al. 2011

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

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Section: Gly Zn(gly) 2 and Complex (1)mentioning

confidence: 79%

Utilization of IR spectral detailed analysis for coordination mode determination in novel Zn–cyclen–aminoacid complexes

Vargová

Almáši

Arabuli

et al. 2011

Spectrochimica Acta Part A: Molecular and Biomolecular Spectros

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“…This behaviour is more pronounced with the third row elements 2 . On this account, the cadmium-glycine interactions have been studied 3,4 . The aim of this publication is to report the synthesis and characterization of adducts of general formula MCl 2 .ngly, where M= Mn and Cu; n= 2 and 4, and gly= glycine.…”

Section: Introductionmentioning

confidence: 99%

Synthesis and characterization of manganese-glycine and copper-glycine adducts

Farias¹

2002

Quím. Nova

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Recebido em 11/6/01; aceito em 20/2/02This work reports the synthesis and characterization of adducts of general formula MCl 2 .ngly, where M= Mn and Cu; n= 2 and 4, and gly= glycine. The manganese adducts were synthesized by dissolution of both, manganese chloride and glycine in water, whereas the copper adducts were obtained by using an alternative solid state synthesis approach. For all adducts, the obtained infrared data shows that the coordination involves the amine nitrogen atom, as well as an oxygen atom of the COO -group. The TG curves for the synthesized adducts exhibit only one mass loss step associated with the release of glycine molecules.

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