We have investigated the longitudinal thermal conductivity of α-RuCl3, the magnetic state of which is considered to be proximate to a Kitaev honeycomb model, along with the spin susceptibility and magnetic specific heat. We found that the temperature dependence of the thermal conductivity exhibits an additional peak around 100 K, which is well above the phonon peak temperature (∼ 50 K). The higher-temperature peak position is comparable to the temperature scale of the Kitaev couplings rather than the Néel temperatures below 15 K. The additional heat conduction was observed for all five samples used in this study, and was found to be rather immune to a structural phase transition of α-RuCl3, which suggests its different origin from phonons. Combined with experimental results of the magnetic specific heat, our transport measurement suggests strongly that the higher-temperature peak in the thermal conductivity is attributed to itinerant spin excitations associated with the Kitaev couplings of α-RuCl3. A kinetic approximation of the magnetic thermal conductivity yields a mean free path of ∼ 20 nm at 100 K, which is well longer than the nearest Ru-Ru distance (∼ 3Å), suggesting the long-distance coherent propagation of magnetic excitations driven by the Kitaev couplings.
IntroductionQuantum spin liquid is a phase of magnetic insulator in which frustration or quantum fluctuation prohibits magnetic order while keeping spin correlation 1-3 . It induces rich physical phenomena depending on the types of spin liquids, which cannot be realized in standard ordered magnets. Several quantum-spin models have been proposed as possible realizations of quantum spin liquids along with candidate frustrated magnets such as κ- ( Among them, the Kitaev honeycomb model is unique in that the ground state is exactly calculated and known to be a two-dimensional (2D) quantum spin liquid 10 . In this model, spin-1/2 moments, S r , sit on a honeycomb lattice and interact via the bond-dependent Ising couplings; different spin components interact via Ising coupling for the three different bonds of the honeycomb lattice. These anisotropic couplings, called the Kitaev couplings J α S