Thermal stability and oxidation resistance of ZrSiN nanocomposite and ZrN/SiNx multilayered coatings: A comparative study

Saladukhin, I.A.; Abadias, G.; Углов, В.В.; Zlotski, S.V.; Michel, A.; Vuuren, A. Janse van

doi:10.1016/j.surfcoat.2017.08.076

Cited by 34 publications

(30 citation statements)

References 52 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…Hard nanocomposite coatings for cutting tools may generally be classified into two groups: [137], nc-TiC + a-C [138,139] Ti-Si-N [140,141], Ti-Si-B-C [142][143][144], Ti-Si-B-C-N [145], AlTiN-Ni [146], ZrN/SiN x [147], nc-W 2 N/a-Si 3 N 4 [148], (Zr-Ti-Cr-Nb)N [149,150], Mo 2 BC [151], nc-AlN/a-SiO 2 [152]. In particular, several of these coatings, such as Ti-Al-Si-N, Ti-Si-N and AlTiN-Ni, were deposited and tested on cemented carbide WC-Co-based substrates like in [135,136,140,146].…”

Section: Nanocomposite Super-hard Coatingsmentioning

confidence: 99%

The Critical Raw Materials in Cutting Tools for Machining Applications: A Review

et al. 2020

View full text Add to dashboard Cite

A variety of cutting tool materials are used for the contact mode mechanical machining of components under extreme conditions of stress, temperature and/or corrosion, including operations such as drilling, milling turning and so on. These demanding conditions impose a seriously high strain rate (an order of magnitude higher than forming), and this limits the useful life of cutting tools, especially single-point cutting tools. Tungsten carbide is the most popularly used cutting tool material, and unfortunately its main ingredients of W and Co are at high risk in terms of material supply and are listed among critical raw materials (CRMs) for EU, for which sustainable use should be addressed. This paper highlights the evolution and the trend of use of CRMs) in cutting tools for mechanical machining through a timely review. The focus of this review and its motivation was driven by the four following themes: (i) the discussion of newly emerging hybrid machining processes offering performance enhancements and longevity in terms of tool life (laser and cryogenic incorporation); (ii) the development and synthesis of new CRM substitutes to minimise the use of tungsten; (iii) the improvement of the recycling of worn tools; and (iv) the accelerated use of modelling and simulation to design long-lasting tools in the Industry-4.0 framework, circular economy and cyber secure manufacturing. It may be noted that the scope of this paper is not to represent a completely exhaustive document concerning cutting tools for mechanical processing, but to raise awareness and pave the way for innovative thinking on the use of critical materials in mechanical processing tools with the aim of developing smart, timely control strategies and mitigation measures to suppress the use of CRMs.

show abstract

Section: Nanocomposite Super-hard Coatingsmentioning

confidence: 99%

The Critical Raw Materials in Cutting Tools for Machining Applications: A Review

et al. 2020

View full text Add to dashboard Cite

show abstract

“…It can be observed clearly that the extent of oxidation destruction are severer in the coatings with higher oxygen content and the coatings tend to be peel off from the substrate. The strong detriment of the high-temperature oxidation resistance of the as-deposited coatings may attribute to the lack of the nanocomposite structure [10,22,23]. Figure 8 shows the SEM images and EDS spectra of Cr-Si-O-N coatings with the oxygen flow ratio of 2% and 10% after annealing.…”

Section: Microhardness High Temperature Test and Corrosion Testmentioning

confidence: 99%

Influence of Oxygen Contents on the Microstructure, High Temperature Oxidation and Corrosion Resistance Properties of Cr–Si–O–N Coatings

et al. 2018

View full text Add to dashboard Cite

Abstract:Cr-Si-O-N coatings with different oxygen contents were deposited by multi-arc ion plating, where various O 2 /(N 2 + O 2 ) reactive gas rates were adopted. The XRD and XPS results showed that the CrN crystals disappeared with the increasing of the oxygen flux ratio to 10 at.%. The microhardness of all the Cr-Si-O-N coatings was approximately 2000 Hv 0.05 , which were dramatically plummeted compared to that of the Cr-Si-N coatings (≈3300 Hv 0.05 ). The Cr-Si-O-N coatings were annealed under 800 • C and 1200 • C in the air atmosphere for 2 h to study the high-temperature oxidation resistance of the coatings. Meanwhile, Cr-Si-O-N coatings with different O 2 /(N 2 + O 2 ) rates were also used to carry out the corrosion resistance testing using the electrochemical working station in 3.5% NaCl solution under free air condition at room temperature. The results indicated that the coatings containing oxygen were more vulnerable to the high-temperature destruction and more easily corroded in the NaCl electrolyte.

show abstract

“…ZrN system is sufficiently stable at temperatures not exceeding 850 °C, but at higher temperatures, grains start to grow and that leads to a significant decrease in hardness [3]. When temperature is raised up to 550 °C, the process of active oxidation starts, during which tetragonal t-ZrO2 are formed, and at temperatures exceeding 950 °C, monoclinic (m-ZrO2) are formed [4]. (Zr,Al)N system maintains its stable hardness up to temperature of 1100 °C [3].…”

Section: Introductionmentioning

confidence: 99%

“…The addition of silicon led to an increase in hardness of coatings. An increase in hardness was explained in the framework of a two-step mechanism, i.e., by forming a solid solution of Si atoms in NbN [22], TiN [22], ZrN [4], CrN [23], (Ti,Al)N [24], (Zr,Al)N [25], (Cr,Al)N [26], (Ti,Zr)N [27], (Ti,Cr)N [28], (Cr,Ti,Al)N [28], lattice and by forming a nanocomposite material. Addition of Si can also decrease penetrating of reactive agents into the coatings through the refine effect [29].…”

Section: Introductionmentioning

confidence: 99%

“…Addition of Si can also decrease penetrating of reactive agents into the coatings through the refine effect [29]. The incorporation of hard nanocrystalline TiAlN phases with improved oxidation resistance, and Si3N4 amorphous phase achieving superhardness, has allowed increasing the hardness as well as thermal stability [3,4] Other option for both improvement of mechanical characteristics and increase in a resistance to high-temperature oxidation is the formation of multilayered coating structures [4,20,30]. The properties of multilayered nano-structured coatings Ti-TiN-(TiCrAl)N, Zr-(Zr,Cr)N-CrN, Ti-TiN-(Ti,Cr,Al)N, Ti-(AlCr)N-(TiAl)N, Ti-(AlCr)N-(TiCrAl)N, Zr-(AlCr)N-(ZrCrAl)N, Ti-TiN-(TiCrAl)N, Zr-ZrN-(ZrNbCrAl)N are investigated in [32][33][34][35][36][37][38][39][40][41][42].…”

Section: Introductionmentioning

confidence: 99%

See 1 more Smart Citation

Effect of adhesion and tribological properties of modified composite nano-structured multi-layer nitride coatings on WC-Co tools life

Vereschaka

Aksenenko

Sitnikov

et al. 2018

Tribology International

View full text Add to dashboard Cite

Effect of adhesion and tribological properties of modified composite nanostructured multi-layer nitride coatings on WC-Co tools life http://researchonline.ljmu.ac.uk/id/eprint/9965/ Article LJMU has developed LJMU Research Online for users to access the research output of the University more effectively. Citation (please note it is advisable to refer to the publisher's version if you intend to cite from this work) Vereschaka, A, Aksenenko, A, Sitnikov, N, Migranov, M, Shevchenko, S, Sotova, C, Batako, ADL and Andreev, N (2018) Effect of adhesion and tribological properties of modified composite nano-structured multi-layer nitride coatings on WC-Co tools life. Tribology International, 128. pp. 313-Abstract:The paper presents the results of the comparative tests of carbide samples with multilayered nano-structured coatings based on titanium nitrides (Ti-TiN-(Ti,Cr,Al,Si)N) and zirconium nitrides (Zr-ZrN-(Nb,Zr,Cr,Al)N and Zr-ZrN-(Zr,Al,Si)N). The phase composition and microstructure of these coatings were studied. The scratch test method was applied to study the adhesion bond strength to the substrate and the coating fracture patterns. The tribological parameters of the coated samples were studied at temperatures of 450°C-900 °C. The cutting properties of the tools with the coatings under study were investigated in turning AISI 321 steel. Various coating parameter effects on the cutting tool life were studied.

show abstract

Thermal stability and oxidation resistance of ZrSiN nanocomposite and ZrN/SiNx multilayered coatings: A comparative study

Cited by 34 publications

References 52 publications

The Critical Raw Materials in Cutting Tools for Machining Applications: A Review

The Critical Raw Materials in Cutting Tools for Machining Applications: A Review

Influence of Oxygen Contents on the Microstructure, High Temperature Oxidation and Corrosion Resistance Properties of Cr–Si–O–N Coatings

Effect of adhesion and tribological properties of modified composite nano-structured multi-layer nitride coatings on WC-Co tools life

Contact Info

Product

Resources

About