2014
DOI: 10.1007/s10973-014-4290-5
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Thermal stability and degradation of selected poly(alkyl methacrylates) used in the polymer industry

Abstract: This article describes our results for the thermal stability and thermal degradation of poly(alkyl methacrylates) based on selected methacrylate monomers, namely methyl methacrylate, butyl methacrylate, and 2-ethylhexyl methacrylate, which are used in the polymer industry in the manufacture of construction polymers, polymeric films, and a wide range of adhesives. Quantitative analyses of the thermal degradation products of poly(methyl methacrylate), poly(butyl methacrylate), and poly(2-ethylhexyl methacrylate)… Show more

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Cited by 23 publications
(13 citation statements)
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“…5). Similar behavior was reported for VA/BA copolymer prepared by free radical mechanism [56,77]. Influence of VA/BA ratio on the copolymers VA/BA copolymers have higher thermal stability compared with a polyvinyl acetate and poly(n-butyl acrylate) alloy [56].…”
Section: Effect Of Pdms Surfactant On the Particle Morphologysupporting
confidence: 78%
“…5). Similar behavior was reported for VA/BA copolymer prepared by free radical mechanism [56,77]. Influence of VA/BA ratio on the copolymers VA/BA copolymers have higher thermal stability compared with a polyvinyl acetate and poly(n-butyl acrylate) alloy [56].…”
Section: Effect Of Pdms Surfactant On the Particle Morphologysupporting
confidence: 78%
“…However, according to Grassie [26], polymers of higher esters tend to degrade only partially to monomer, and lead to poorer yields of the monomer. According to Czech et al [27], the general mechanism of the thermal degradation of poly(alkyl methacrylates) consists of random main-chain scission reactions. The principal products resulting from pyrolysis occurring between 200 and 400 • C are methacrylate monomers.…”
Section: Introductionmentioning
confidence: 99%
“…s 2022, 14, x FOR PEER REVIEW second degradation stage represents the degradation of A and B into small monom ecules [33,34]. The resin produced an alkyl methacrylate monomer and a small nu other decomposition products, such as carbon monoxide, carbon dioxide, ethane nol, ethanol, and 1-propanol [35,36]. With the continuous fracture of the end-grou ture, and the decomposition products volatilizing, the weight loss gradually incr 3.4.2.…”
Section: Thermogravimetric Analysis Of Organic Vehiclesmentioning
confidence: 99%