2019
DOI: 10.1016/j.supflu.2019.104602
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Thermal stability and decomposition behavior of HFO-1234ze(E) as a working fluid in the supercritical organic Rankine cycle

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Cited by 26 publications
(7 citation statements)
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“…The energy barriers for the decomposition of the following 4 paths on the surface of Cu(1 1 1) are calculated. Paths 1-4 are the main initial reaction paths of HFO-1234yf [13,14]. Path 1 HFO-1234yf→CF=CH2 + CF3 Path 2 HFO-1234yf→CF3CF=CH + H Path 3 HFO-1234yf→CF3C=CH2 + F Path 4 HFO-1234yf→CF2CF=CH2 + F…”
Section: Resultsmentioning
confidence: 99%
“…The energy barriers for the decomposition of the following 4 paths on the surface of Cu(1 1 1) are calculated. Paths 1-4 are the main initial reaction paths of HFO-1234yf [13,14]. Path 1 HFO-1234yf→CF=CH2 + CF3 Path 2 HFO-1234yf→CF3CF=CH + H Path 3 HFO-1234yf→CF3C=CH2 + F Path 4 HFO-1234yf→CF2CF=CH2 + F…”
Section: Resultsmentioning
confidence: 99%
“…Specifically, they found that the pyrolysis products included coke, macromolecular products, the isomer of HFO-1336mzz (Z), and HF. In addition, the temperature of HFO-1234ze (E) for its safe use was also investigated by Irriyanto et al, 41 and the results showed that HFO-1234ze(E) could be maintained as thermally stable up to 180 C at 5 MPa.…”
Section: F-containing Working Fluidsmentioning
confidence: 99%
“…Nonetheless, in horizontal flow configurations, supercritical fluids are susceptible to encountering heat transfer deterioration, resulting in local increases in wall temperature and potential thermal decomposition of the organic fluid. This poses challenges to the safety [6] and stability of the supercritical system [7,8]. Consequently, enhancing convective heat transfer in horizontal tubes under supercritical conditions becomes a critical approach to improving the heat exchange capacity of the heat exchanger and optimizing the overall efficiency of T-ORC systems.…”
Section: Introductionmentioning
confidence: 99%