“…3 , 4 This for the enhanced rate of singlet-triplet transitions. This behavior of DTBN is contrasted with triplet quenching by other paramagnetic species, and several potential applications to photochemistry are discussed.…”
The overall rate constants (k,) for the quenching of a number of aromatic hydrocarbon and ketone triplets by di-tert-butyl nitroxide (DTBN) in fluid solution have been measured. The values of k , decrease in ( I ) Part I: R.
“…3 , 4 This for the enhanced rate of singlet-triplet transitions. This behavior of DTBN is contrasted with triplet quenching by other paramagnetic species, and several potential applications to photochemistry are discussed.…”
The overall rate constants (k,) for the quenching of a number of aromatic hydrocarbon and ketone triplets by di-tert-butyl nitroxide (DTBN) in fluid solution have been measured. The values of k , decrease in ( I ) Part I: R.
“…However, with a reasonable degree of certainty a few elementary reactions can be postulated as participating in the overall mechanism. Initiation must occur by an interaction between both reactants, since OF 2 with this ratio the only products formed were Na and HF. As the relative J amount of H 2 went down, F2 and NFs became significant products.…”
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